Synthesis, June 1874, New York, (US) D. LANDINI et al.: " Reaction of Alyl Halides and Methanesulfonates with Aqueous Potassium Fluoride in the Presence of Phase-Transfer Catalysts: a Facile Synthesis of Primary and Secondary Alkyl Fluorides ", pages 428-430 (cited in the application)...
The reaction of the bis(1,2-dicyanoethylenedithiolato)lead(II) ion, Pb(mnt) 2− 2, with various organohalides has been examined and found to yield the halo(1,2-dicyanoethylenedithiolato)lead(II) ion Pb(mnt)X − (X = Br, I) and the 1,2-di(alkylmercapto) 1,2-dicyanoethylene...
Intermolecular Heck reaction of common alkyl halides, a longstanding problem in palladium catalysis, is realized with a simple Pd/dppf catalyst. Both primary and secondary alkyl halides are suitable for coupling with aromatic olefins. Single electron transfer from (dppf)Pd0to alkyl halide initiated the...
A novel stereoselective one-pot conversion of alcohols into alkyl halides mediated by N,N'-diisopropylcarbodiimide. Alcohols can be converted in high yields to the corresponding alkyl halides in a one-pot procedure via the corresponding O-alkylisourea; very short reactio... Stefano,Crosignani,Bri...
45%ethanolsolutioninwater Thedataobtainedwillbehandledgraphicallytoobtainarateconstantandcalculatethehalf-life ofthereactionforeachsolventsystem.Comparisonofthevaluesinthetwosolventsshouldgive insightintotheeffectofsolventpolarityonthemechanismandtherateofthereactionofthe hydrolysisreaction. Becausethealkylhalides...
A cobalt complex, [CoCl2(dpph)] (DPPH = [1,6-bis(diphenylphosphino)hexane]), catalyzes an intermolecular styrylation reaction of alkyl halides in the presence of Me3SiCH2MgCl in ether to yield β-alkylstyrenes. A variety of alkyl halides including alkyl chlorides can participate in the styry...
Light-driven C–O coupling of carboxylic acids and alkyl halides over a Ni single-atom catalyst Article 15 June 2023 Data availability The data that support the findings of this study are available within the paper and its supplementary information files. The X-ray crystallographic coordinates ...
Remarkably, the 1,6-dihydropyridazines bearing alkyl groups such as isopropyl, tert-butyl and cyclohexyl substituents, were well tolerated to deliver the desired products 15f-15h in high yields (76–87%). It has recently been documented that the pyridazine derivatives, such as diazinium salts ...
Visible light-induced room-temperature Heck reaction of functionalized alkyl halides with vinyl arenes/heteroarenes. Angew. Chem. Int. Ed. 56, 14212–14216 (2017). Article CAS Google Scholar Wang, G.-Z., Shang, R., Cheng, W.-M. & Fu, Y. Irradiation-induced Heck reaction of ...
R1, R2are each hydrogen (H), alkyl such as C1-20-alkyl, cycloalkyl such as C3-12-cycloalkyl, alkoxyalkyl such as C2-30-alkoxyalkyl, dialkylaminoalkyl such as C3-30-dialkylaminoalkyl, aryl, aralkyl such as C7-20-aralkyl, and alkylaryl such as C7-20-alkylaryl, or together are —(...