The radical ring-opening polymerization (RROP) behavior of the following monomers is reviewed, and the possibility for application to functional materials is described: cyclic disulfide, bicyclobutane, vinylcyclopropane, vinylcyclobutane, vinyloxirane, vinylthiirane, 4-methylene-1,3-dioxolane, cyclic ...
The radical ring-opening polymerization (rROP) ofα-lipoic acid (LA) and its derivatives represents a synthetically accessible, efficient, and scalable strategy to impart degradability into functional copolymers. This review highlights recent advances in the design of sustainable materials containing LA ...
Adhesives with both robust adhesion and tunable degradability are clinically and ecologically vital, but their fabrication remains a formidable challenge. Here we propose an in situ radical ring-opening polymerization (rROP) strategy to design a backbone
Therefore, the development of new systems with low volume shrinkage via radical polymerization is desirable. Radical ring-opening polymerizations (RROP) of cyclic monomers, such as cyclic allyl sulfides, spiro-dixylene,2 vinylcycropropane,3 unsaturated spiroorthocarbonates,4 cyclic ketene acetals5–...
Well-defined AB(2) 3- and AB(4) 5-miktoarm star copolymers were prepared by combination of ring-opening polymerization (ROP) and nitroxide-mediated radical... Y Miura,Y Sakai,K Yamaoka - 《Macromolecular Chemistry & Physics》 被引量: 76发表: 2005年 Kinetic study of H-atom transfer in ...
The radical ring-opening polymerization (RROP) behavior of the following monomers is reviewed, and the possibility for application to functional materials is described: cyclic disulfide, bicyclobutane. vinylcyclopropane, vinylcyclobutane, vinyloxirane, vinylthiirane, 4-methylene-1,3-dioxolane, cyclic ...
Radical Ring‐opening polymerization (RROP) of cyclic ketene acetals (CKAs) emerges to be a valuable polymerization technique. In attracting more attention, RROP has seen a new spike in publications, which the authors will put into perspective. This review will hence address ...
However, its major drawback is that it typically yields polymers with non‐functional, non‐degradable all‐carbon backbones—a limitation that radical ring‐opening polymerization (rROP) allows to overcome. The last decade has seen a surge in rROP, primarily focused on creatin...
Agarwal S. Chemistry, chances and limitations of the radical ring-opening polymerization of cyclic ketene acetals for the syn- thesis of degradable polyesters. Polym Chem. 2010;1:953-64.Agarwal S. Chemistry, chances and limitations of the radical ring- opening polymerization of cyclic ketene ...
Radical ring-opening polymerization (rROP) of cyclic ketene acetals (CKAs) combines the advantages of both ring-opening polymerization and radical polymerization thereby allowing the robust production of polyesters coupled with the mild polymerization conditions of a radical process. rROP was recently ...