ring‐opening polymerizationcyclic monomerThe radical ring-opening polymerization (RROP) behavior of the following monomers is reviewed, and the possibility for application to functional materials is described: cyclic disulfide, bicyclobutane, vinylcyclopropane, vinylcyclobutane, vinyloxirane, vinylthiirane, 4...
RADICAL POLYMERIZATIONRADICAL RING-OPENING POLYMERIZATIONPOLYMERIZATION BEHAVIORVINYLOXIRANEHALOGENATEDPHENYL-3-VINYLOXIRANEPolymer Journal, official journal of the Society of Polymer Science, Japan publishes high quality papers in all areas of polymer and macromolecular research....
On the other hand, the polymerization of 4 in a 50% (by weight) benzene solution at 110掳C with di-tertbutyl peroxide as the catalyst gave quantitative ring opening to give a polyester containing both possible isomeric ring-opened units. Bulk polymerization of 4 at 60掳C at 53% conversion...
2) Free radical ring opening polymerization 自由基开环聚合反应3) Radical polymerization 自由基聚合 1. The Effect of Diffusion on Radical Polymerization; 自由基聚合中扩散效应分析 2. Study on radical polymerization of VAc initiated by naphthalene lithium complex; 萘锂络合物引发醋酸乙烯自由基聚合...
First, the radical ring-opening polymerization of monofunctional 2-phenyl-3-vinyloxirane was investigated. Then, we synthesized di- and trifunctional vinyloxiranes and examined the networked polymer synthesis via the radical ring-opening homopolymerization or copolymerization of these monomers. The ...
Liu W, Mike F, Guo Y, et al. Free-radical polymeriza- tion of dioxolane and dioxane derivatives: effect of fluorine substituents on the ring opening polymerization[J]. Journal of Polymer Science Part A: Polymer Chemistry,2004, 42 (20): 5180-5188....
theirbackbonel'Z-'0l,andpolymersWithlowvolumeshrinkageduringring-openingpolymerizationcanbe achieved",一,'I.Generally,thepolymersthusobtainedhadlowmolecularweightandbroadmolecularweight distribution.Therefore,itwouldbevery interestingtorealizecontrolleWTving"radicalring-opening polymerization.ItwasreportedbyWeil'sltha...
网络释义 1. 自由基环化反应 ...炔烃经分子内(英语:intramolecular)自由基环化反应(英语:radical cyclization)反应氧化成酮,且自由基是无机而非有 … zh.wikipedia.org|基于4个网页 2. 自由基环合 自由基开环聚合,Free... ... ) Free radical ring opening polymerization 自由基开环聚合反应 )Radical cyclizat...
1 1ReactionsofRadicalPolymerization 2 ElementaryReactionsofRadicals 1）Addition(加成)CH3+CH2CH2 CH3CH2CH2 .2)Transfer(转移)3）Coupling(偶合）CF3+CH4 CF3H+CH3 R+R R R 4）Disproportionation（歧化）.CH3+CH3CH2 5）Fragmentation（分解）CH3CO CH4+CH2 CH2 CH3+CO 3 ReactionsofPolymerization fast/slow...
Atom transfer radical polymerization (ATRP) and ring opening polymerization (ROP) were combined to synthesize various polymers with various structures and ... K Matyjaszewski - 《Encyclopedia of Materials Science & Technology》 被引量: 5372发表: 2001年 Living Radical Polymerization by the RAFT Process...