Gennaro A, Romanin AM, Severin MG, Vianello E (1984) Radical–radical coupling in the electrochemical reduction of isophthalonitrile. J Electroanal Chem 169(1–2):279–285A. Genn aro, A.M. Romanin, G .M . Severin, E. Vianello, Radical - radical coupling in the electro- chemical ...
Radical-coupling 例句 释义: 全部 更多例句筛选 1. The mechanism shows that the reactions proceeded via radical coupling or redox-radical coupling way. 反应的机理可能是通过自由基偶联或氧化还原-自由基偶联的方式进行。 www.lunwenwa.com© 2025 Microsoft 隐私声明和 Cookie 法律声明 广告 帮助 反馈...
The electrochemical reduction mechanism of isophthalonitrile (1,3-benzenedicarbonitrile) has been investigated by cyclic voltammetry and polarography. In anhydrous DMF, the anion radical formed by quasi-reversible one-electron transfer undergoes dimerisation through radical—radical coupling. Comparison of the...
Radical intermediates are key species in many chemical transformations. Recent advances have provided a new suite of selective radical alkylation reactions. This Comment highlights pioneering studies using alkyl amines that act as radical precursors in a
1) radical coupling 自由基偶合 2) free-radical Coupling 自由基偶联 3) Radical polymerization 自由基聚合 1. The Effect of Diffusion on Radical Polymerization; 自由基聚合中扩散效应分析 2. Study on radical polymerization of VAc initiated by naphthalene lithium complex; ...
Enzymatic catalysis meets radical coupling doi:10.1038/s41929-025-01290-0Nature Publishing Group UKNature CatalysisChenyu WangScientific Reports
A new method was demonstrated to overcome the selectivity issue of radical–radical cross-coupling toward the synthesis of asymmetric diaryl thioethers. The preliminary mechanism was revealed by radical-trapping experiments, DFT calculations, and kinetics, etc., indicating that the C–S bond formed th...
1) free-radical Coupling 自由基偶联2) radical coupling 自由基偶合3) radical cross linking 自由基交联 例句>> 4) tandem radical reaction 自由基串联5) homocoupling 自身偶联 1. By screening different organic solvents, it was found that NiCl_2·6H_2O can catalyze the homocoupling of ...
Radical cross-coupling reactions represent a revolutionary tool to make C(sp3)–C and C(sp3)–heteroatom bonds by means of transition metals and photoredox or electrochemical approaches. However, the use of main-group elements to harness this type of rea
Depending on the reaction conditions the radical intermediate is trapped stereoselectively by TEMPO, or undergoes a dimerization reaction. 关键词: asymmetric reactions carbanions electron transfer radicals and radical reactions DOI: 10.1016/S0040-4039(99)00664-4 被引量: 42 年份: 1999 ...