The presence of only trans-isomers in the solid phases was deduced in the case of [PdCl2(SPh2)2] and [PdCl2(SePh2)2] (1t and 2t, respectively). By contrast, the Rietveld refinement of the powder X-ray diffraction diagrams of [PtCl2(SPh2)2] and [PtCl2(SePh2)2] indica...
We confirmed suitability of the three selected functionals for reproduction of the experimental structure of Pt complexes at fourth oxidation state by using the cis- and trans - Pt(IV)(en) 2 Cl 2 2 + ions as models. Finally, with the selected theoretical methods, the structures and ...
E xp erim en ta l 1 .1 R eagen ts C/s一[Pt(NH3)2Cl2] and 4,4 一methylenedianiline (L) were purch ased from Sigma—A ldri ch ; glu tathione (GSH),disodium salt of guanosine一5 一monophosphate (5 一GMP) and ascorbic acid were from Sigma.Cis一[Pt ...
The interaction of the clathrate Pt 6 Cl 12 路 0.1 EtCl 路 5.7H 2 O with RCN nitriles results in cis-[Pt(PhCH 2 CN) 2 Cl 2 ] and in [Pt(RCN) 2 Cl 2 ] (R = CH 2 CO 2 Et, Ph) complexes as a mixture of cis- and trans-isomers which separated and characterized. Cis-...
Einbau der Benzonitril-Liganden des Cl2Pt(NCC6H5)2 in einen Phosphor—Stickstoff-Chelatringdoi:10.1016/S0022-328X(00)91426-8By treatment of Cl2Pt(NCC6H5)2 with 2 mol of R2P(NR)NRLi, R = CH3, a mixture of cis and trans isomers of the new six-membered phosphorus—nitrogen chelate ...
The complexes (1) and (2) were synthesized in a similar way. In a typical experiment, 0.1 mmol of [Pt(en)Cl2] was dissolved in 3 mL of DMF in a 10 mL a vial, followed by the addition of 0.095 mmol of AgNO3. The mixture was left at room temperature overnight in the dark, and...
In contrast to this, CˆNˆN cyclometalated complexes using the 2,2 :6 ,3 - and 2,2 :6 4 -terpy isomers were not obtained. Comparison of the NˆCˆN complexes of the cyclometalated 2,3 :5 ,2 - and 2,2 :4 ,2 -terpy ligands with complexes [M(dpb)Cl] of the ...
This intermediate is thought to undergo a Me-to-Pd-olefin bond migratory insertion, leading to a cyclometalated product, which undergoes further re-arrangement reactions to finally form a η3-allyl Inorganics 2015, 3 124 complex [(Me2-Xyl-DAB)Pd(η3-6-methyloct-2-en-1-id)][SbF6] with ...
Cis and trans isomers of Pt(SiHAr2)2(PR3)2 (R = Me, Et) in the solid state and in solutions. Organometallics 1999, 18, 1349–1352. [CrossRef] 15. Braddock-Wilking, J.; Corey, J.Y.; Trankler, K.A.; Xu, H.; French, L.M.; Praingam, N.; White, C.; Rath, N.P. ...
Heptane isomerization to branched isomers with high octane numbers is a desirable reaction for compensating for the octane number [3,4]. However, no process that is suitable for heptane fraction isomerization in industrial oil refining is currently known; since the implementation of such a process ...