Optical isomers can be defined as two similar compounds which have the same bond arrangement and connectivity but have difference in their spatial arrangements which results in the formation of non-superimposable mirror images. These non-superimposable mirror images are known as ena...
1.The circular dichroism (CD) spectra of optical isomers of EnPyClNO2ClPtCl and its amidodiamine [(En-H)PyClNO2ClPt]H2O were investigated in various solvents (water, alkaline aqueous solution, dimethylformamide, pyridine).2.The CD spectrum of EnPyClNO2ClPtCl in alkaline aqueous solution ...
isomers (Table 2); a similar effect was previously reported for Ir(III) complexes [37]. When the complexes are studied in dilute fluid solutions, different conformations are thermally accessible and possess comparable excited state characters yet different deactivation rates; therefore, multiexponential...