Through-space interactionsA series of N -aryl-3,4-(9′,10′-dihydroanthracene-9′,10′-diyl)succinimides have been synthesized as model compounds to study the interaction of an aromatic π system with aliphatic H atoms and heteroatoms such as oxygen, sulfur, and fluorine. The steric ...
H. (1999), The Striking Influence of Intramolecular Lanthanoid–π–Arene Interactions on the Structural Architecture of the Homoleptic Aryloxolanthanoid(II) Complexes [Eu2(Odpp)(μ-Odpp)3] and [Yb2(Odpp)2(μ-Odpp)2] and the YbII/YbIII Trimetallic [Yb2(μ-Odpp)3]+[Yb(Odpp...
Heterogeneous perturbations2E+ ~ 2Π of largely different magnitudes are observed with high resolution in the vacuum-ultraviolet absorption and in the infrared emission spectrum of the NO molecule. The rotational interactions between2Σ+Rydberg states and levels of theB2Π non-Rydberg state are ...
With the help of the theory of long-range interactions, an improved value for the ground state dissociation energy is obtained,viz.D0″ = 22 184 ± 3 cm−1 (≡ 63.427 ± 0.008 kcal/mole ≡ 2.7504 ± 0.0004 eV).J. A. Coxon...
Francesc Teixidor ProfClara Viñas DrReijo Sillanpää ProfRaikko Kivekäs DrR. Nun˜ez et al., A Discrete P-I-I-P Assembly: The Large Influence of Weak Interactions on the 31P NMR Spectra of Phosphane-Diiodine Complexes, Angew. Chem. Int. Edit. 45 (2006) 1270....
cation–π interactionsC—H … O H-bonding interactionsIt is generally understood that helical proteins are stabilized by a combination of hydrophobic and packing interactions, together with H-bonds and electrostatic interactions. Here we show that polar side-chain interactions on the surface can play...
The3Π and3Σ states fine structure has been interpreted by a simple model, which includes spin–spin, and second-order spin–orbit interactions and also centrifugal distortion effects both on rotational and spin–orbit coupling parameters. The ν dependence of the different molecular parameters has...
As a result, samples can be run in a mobile phase suitable for the polymer rather than selecting conditions to minimise column interactions which leads to the risk of aggregate formation in polyelectrolytes. While it is possible to calculate the MW of a polymer eluting from an FFF channel...