甚至说the terms "pi-stacking" or "pi–pi interactions" do not describe any physically meaningful...
2)后半句话的大致意思是,生物炭以物理吸附(而非化学反应)为主,并给出了几个烂大街的物理吸附方...
Arnstein, S. A.; Sherrill, C. D. Substituent effects in parallel-displaced π-π interactions. Phys. Chem. Chem. Phys. 2008, 10, 2646-2655.Substituent effects in parallel-displaced pi-pi interactions. Arnstein Stephen A,Sherrill C David. Physical chemistry chemical physics : PCCP . 2008...
Comprehensively revealing the unique pi-pi interactions between different cyclocarbon and fullerene! 文/Sobereva@北京科音2024-Oct-28 0 前言 18碳环以其独特的几何和电子结构,自从2019年在凝聚相观测到后引发了化学界的巨大关注。与之相关的分子间相互作用文章已有不少,例如《全面探究18碳环独特的分子间相互作用...
The recent surge of interest in the control of molecular organization in both the solution state (i.e. self-assembly) and the solid state (i.e. crystal engineering) has led researchers to recognize increasingly the importance of weak noncovalent interactions. The design and synthesis of an effic...
3.1.2 π-π interactions The π-π interactions are one of the most fascinating and highly important noncovalent interactions in the carbonaceous materials like graphene, CNTs, fullerenes etc. due to the fact that the electrically neutral yet negatively rich electrostatic π regions of the interacting...
That’s where Pi - Phase Interactions Mixer steps in. Pi works behind the scenes to optimize phase relationships between tracks, ensuring they complement each other to prevent those frustrating cancellations. Just drop Pi into the last insert slot on each channel, and it’ll do the heavy liftin...
–CH3, and so on) would lead to the dense π-electron density, and hinder π–π interactions...
我也认为楼主的说法有点问题,orbital interactions 在常见的atom-atom相互作用中并非主导的。能量分解分析...
Pignatello, Pi(+)-pi interactions between (hetero)aromatic amine cations and the graphitic surfaces of pyrogenic carbonaceous materials, Environ. Sci. Technol. 49 (2015) 906-914... F Xiao,JJ Pignatello - 《Environmental Science & Technology Es & T》 被引量: 42发表: 2015年 pi(+)-pi Inter...