Site‐Selective, Modular Diversification of Polyhalogenated Aryl Fluorosulfates (ArOSO2F) Enabled by an Air‐Stable PdI Dimeraryl fluorosulfatescatalysischemoselectivityDFT calculationsdinuclear PdSince 2014, the interest in aryl fluorosulfates (ArOSO F) as well as their implementation in powerful ...
Sequential and triply selective arylations and alkylations were realized within minutes at room temperature, using a single and air‐stable PdI dimer.doi:10.1002/anie.201911465Marvin MendelInstitute of Organic Chemistry RWTH Aachen University Landoltweg 1 52074 Aachen GermanyIndrek Kalvet...