palladium-catalyzed hydrogenationpalladium-catalyzed hydrometallationpalladium-catalyzed isomerizationSummary The authors present a concise discussion of heterogeneous Pd-catalyzed hydrogenation and a brief discussion of Pd-catalyzed homogeneous hydrogenation. The chapter explores the synthetic methods developed for ...
2804VIICATALYTICHYDROGENATIONANDOTHERPd-CATALYZEDREACTIONS 1.Besidesbeingconsiderablyfasterandfacile,thePd-catalyzedhydrostannationis significantlymorestereoselectiveinvolvingapredominantorexclusivesyn-additionof H—Snbondstoalkynes.Evenso,thestereoselectivityoftenisbelow90%. 2.Proximalheteroatoms,suchasSi,N,O,S,andha...
Homogeneous palladium-catalyzed asymmetric hydrogenation. Qing-An Chen,Zhi-Shi Ye,Ying Duan,Yong-Gui Zhou. Chemical Society Reviews . 2013Homogeneous palladium-catalyzed asymmetric hydrogenation. Chen,Q,Ye,Z,Duan,Y,Zhou,Y. Chemical Society Reviews . 2013Homogeneous palladium-catalyzed asymmetric ...
In summary, we have discovered an efficient electrohydrogenation of N2to NH3on Pd/C catalyst at an overpotential as low as 56 mV for the electrochemical NH3synthesis under ambient conditions. The Pd/C catalyst exhibits high activity and selectivity for N2RR in a PBS electrolyte, achieving an ...
A SIMPLIFIED HYDROGENATION TECHNIQUE FOR THE DETERMINATION OF BLOOD PLASMA TOCOPHEROLS A simple apparatus was devised which allowed the passage of hydrogen at controlled pressure into 50 ml. conical centrifuge tubes. Plasma extracts for the e... ML Quaife,R Biehler - 《Journal of Biological Chemistry...
4.The Application of Palladium-Catalysts in Hydrogenations and Aqueous Reactions钯催化剂在催化氢化和水相反应中的应用 5.Synthesis of High Dispersion Palladium Catalyst and the Research of Catalysis Property;高分散钯催化剂的制备及催化性能研究 6.Study on the Catalytic System of Palladium Prepared from Mi...
Selective hydrogenation by Pd nanoparticles embedded in polyelectrolyte multilayers. Alternating adsorption of poly(acrylic acid) and a polyethylenimine-Pd(II) complex on alumina and subsequent reduction of Pd(II) by NaBH4 yield catalytic Pd nanoparticles embedded in multilayer polyelectrolyte films. The ...
& Lu, Z. Regio- and enantioselective cobalt-catalyzed sequential hydrosilylation/hydrogenation of terminal alkynes. Angew. Chem. Int. Ed. 56, 615–618 (2017). Article CAS Google Scholar Wen, H., Wan, X. & Huang, Z. Asymmetric synthesis of silicon-stereogenic vinylhydrosilanes by cobalt-...
Asymmetric hydrogenation of methyl-(Z)-α-acetamidocinnamate catalyzed by {1,2-bis(phenyl-0-anisoyl)phosphino)ethane}rhodium(I): kinetics, mechanism, and origin of enantioselection Reaction of Na2PdCl4 with N-ferrocenylmethylidene-2,4,6-trimethylaniline yields the dimeric, chloro-bridged Pd(II)...
Extending the Substrate Scope of Bicyclic P-Oxazoline/Thiazole Ligands for Ir-Catalyzed Hydrogenation of Unfunctionalized Olefins by Introducing a Biaryl P... successful generation of bicyclic N-phosphane-oxazoline/thiazole ligands, by replacing the N-phosphane group with a pi-acceptor biaryl phosphor...