palladium-catalyzed hydrogenationpalladium-catalyzed hydrometallationpalladium-catalyzed isomerizationSummary The authors present a concise discussion of heterogeneous Pd-catalyzed hydrogenation and a brief discussion of Pd-catalyzed homogeneous hydrogenation. The chapter explores the synthetic methods developed for ...
In summary, we have discovered an efficient electrohydrogenation of N2to NH3on Pd/C catalyst at an overpotential as low as 56 mV for the electrochemical NH3synthesis under ambient conditions. The Pd/C catalyst exhibits high activity and selectivity for N2RR in a PBS electrolyte, achieving an ...
polyphenylalkene derivatives (stilbene derivativessteroidsVarious successful applications of the hydrogenation catalysts mentioned in the title are outlined in the reaction scheme.doi:10.1002/chin.199017100VILLEMIN, D.LETULLE, M.WILEY‐VCH Verlag GmbHChemInform...
4.The Application of Palladium-Catalysts in Hydrogenations and Aqueous Reactions钯催化剂在催化氢化和水相反应中的应用 5.Synthesis of High Dispersion Palladium Catalyst and the Research of Catalysis Property;高分散钯催化剂的制备及催化性能研究 6.Study on the Catalytic System of Palladium Prepared from Mi...
& Lu, Z. Regio- and enantioselective cobalt-catalyzed sequential hydrosilylation/hydrogenation of terminal alkynes. Angew. Chem. Int. Ed. 56, 615–618 (2017). Article CAS Google Scholar Wen, H., Wan, X. & Huang, Z. Asymmetric synthesis of silicon-stereogenic vinylhydrosilanes by cobalt-...
When these two complexes were used to catalyze the hydrogenation of nitro- and carbonyl-compounds and the compounds containing C=C double bound, it was found that they have higher catalytic activity at room temperature and under atmospheric hydrogen pressure. The hydrogenation of carbonyl-compounds ...
The bis-hydroxylation followed by hydrogenation of ethyl 4-azido-2,3,4-trideoxy-alpha-D-erythro-hex-2-enopyranoside afforded the corresponding 4-amino-alpha-D-mannopyranoside, when propyl 2-azido-2,3,4-trideoxy-alpha-D-threo-hex-3-enopyranoside gave the 2-amino-alpha-D-altropyranoside...
Double-bond migration and cis-trans isomerization reactions occur in the catalytic hydrogenation of octadecenoates. With heterogeneous catalysts, the relat... I Heertje,GK Koch,WJ W?Sten - 《Chemischer Informationsdienst》 被引量: 26发表: 1974年 ChemInform Abstract: Transition-Metal-Catalyzed Carbonyla...
Figure 2. Screening of Ir‐catalysts for the asymmetric hydrogenation of sulfone 1. The detailed screening results in the hydrogenation of 1 ab can be found in the Supporting Information. The best results were obtained using Ir‐Ubaphox C3 (1 mol%) which showed an outstanding 98% ee in...
Hydrogenation of (N,N-disubstituted aminomethyl)nitrobenzenes to (N,N-disubstituted aminomethyl)anilines catalyzed by palladium–nickel bimetallic nanoparticlesHydrogenation of (N,N-disubstituted aminomethyl)nitrobenzenes to (N,N-disubstituted aminomethyl)anilines catalyzed by palladium–nickel bimetallic nanopar...