J. M. WinterbottomDepartment of Chemical Engineering, The University of Birmingham, BirminghamSpringer-VerlagJournal of the American Oil Chemists' SocietyM. Ahmad, T. Priestley, J. Winterbottom, Palladium-catalyzed hydrogenation of soybean oil, J. Am. Oil Chem. Soc. 56 (1979) 571-577....
Palladium-catalyzed transfer hydrogenation of some organic substrates in water containing a nonionic surfactant was examined using sodium hypophosphite as a hydrogen source. Hydrogenation of organohalides such as polychloroarenes, alkenes, alkynes, nitro compounds, aromatic aldehydes, and O-benzyl and N-...
ChemInform Abstract: Hydrogenation Catalyzed by Palladium or Rhodium Chlorides in the Presence of TDA-1reduction, hydrogenationcyclobutane derivativespolyphenylalkane derivativespolyphenylalkene derivatives (stilbene derivativessteroidsVarious successful applications of the hydrogenation catalysts mentioned in the title ...
Moreover, a Pd/C-catalyzed hydrogenation of alkene with H2 balloon led to saturated spirocarbocycle 17 in 92% yield. It is noted that compounds 3a, 16, and 17 are analogs of a patented bioactive molecule for treating pain56, which indicates further potential application of the present method...
SEM–EDX and TEM analyses were performed to determine the structure of the foams and the distribution of Pd nanoparticles (after metal reduction). Metal-sorbent interactions and oxidation state of Pd are characterized by XPS. Pd(0)-bearing foams are investigated for the hydrogenation of 3-...
Further studies to demonstrate the possibility of substrate and stereospecific sites on palladized charcoal hydrogenation catalysts have been made. The rates of hydrogenation of the benzyl esters of (+), (-), (±), and meso -tartaric acids, (±) malic acid, D -, L -, and DL -as...
platinum. Density functional theory calculations suggest that the unique activity of palladium originates from its balanced hydrogen evolution activity and the Grotthuss-like hydride transfer mechanism on α-palladium hydride that lowers the free energy barrier of N2hydrogenation to *N2H, the rate-...
In the past, palladium as a member of the platinum group metals was mainly known as an expensive noble metal. Probably, only fast hydrogen absorption into bulk palladium reminded of its unique catalytic activity. At the beginning of the twenty-first century, detailed studies of the electron stru...
Palladium-catalyzed acylation of unsaturated halides by anions of enol ethers. Asymmmetric Allylation reactions. Intramolecular reactions with alkenes. Carbonylation reactions. Cross Coupling reactions. Chemical Properties purple brown Uses Hydrogenation, isomerization, carbonylation, oxidation, C-C bond formation...
Hydrogenation of (N,N-disubstituted aminomethyl)nitrobenzenes to (N,N-disubstituted aminomethyl)anilines catalyzed by palladium–nickel bimetallic nanoparticlesHydrogenation of (N,N-disubstituted aminomethyl)nitrobenzenes to (N,N-disubstituted aminomethyl)anilines catalyzed by palladium–nickel bimetallic nanopar...