Palladium-catalyzed dehydrogenative coupling of hydropolysiloxanes with amines was investigated. The reactions of alpha,omega-dihydropoly(dimethylsiloxane) with pyrrolidine, piperidine, di(isopropyl) amine, and di(n-butyl) amine in the presence of a catalytic amount of PdCl2 or Pd/C at 50-70 ...
Moreover, the availability of practical and sustainable methods for the transition-metal-catalyzed oxidative dehydrogenation of alkanes to alkenes has been limited due to the requirement of less favorable reaction conditions6,7,8,9. In particular, some strategies describing Pd-catalyzed intramolecular ...
Preparation of PAHs through Palladium-Catalyzed C–H Bond Arylation Preparation of Sulfur-Containing PCHs through Palladium-Catalyzed C–H Bond Arylation Preparation of Oxygen-Containing PCHs through Palladium-Catalyzed C–H Bond Arylation Preparation of Nitrogen-Containing PCHs through Palladium-Catalyzed C...
Hydrogenation of Pyridine to Piperidine Catalyst (1) Isopropylamine synthesis catalyst (1) Ethylamine Synthesis catalyst (1) Morpholine synthesis catalysts (1) Cyclohexylamine catalyst (1) Isopropanol synthesis catalyst (3) Solid Phosphoric Acid Catalyst ...
Miller KJ, Kitagawa TT, Abu-Omar MM (2001) Kinetics and mechanisms of methyl vinyl ketone hydroalkoxylation catalyzed by palladium(II) complexes. Organometallics 20:4403–4412 CAS Google Scholar Baran T, Sargin I, Mentes A, Kaya M (2016) Exceptionally high turnover frequencies recorded for a...
Compounds such as 20 were prepared using a palladium-catalyzed Ullmann cross-coupling reaction between the appropriate 2-iodocyclohex-2-en-1-one and o-halonitrobenzene.关键词: organic chemistry, catalytic activity, palladium, dehydrogenation, chemical structure, organic compounds, cross-coupling reactions...
Palladium nanoparticles (Pd NPs) supported on organoamine-functionalized SBA-15 mesoporous silica are known to have higher catalytic activity for formic acid dehydrogenation than Pd NPs supported on plain, unmodified SBA-15 mesoporous si... T Asefa,K Koh,M Jeon,... - 《Journal of Materials Chem...
Transition metal-catalyzed asymmetric hydrofunctionalizations of unsaturated bonds via π-ƞ3 substitution have emerged as a reliable method to construct stereogenic centers, and mainly rely on the use of heteroatom-based or carbon nucleophiles bearing
reported that the amine-functionalized MIL-125 with imbedded Pd NPs as a catalyst for the dehydrogenation of formic acid at ambient temperature [17]. This paper shows that the amino-functionalized titanium-based MOF, NH2-MIL-125, is an excellent solid support for Pd NPs (Pd@NH2-MIL-125), ...
Modulating the electrocatalytic performance of Palladium (Pd) with nonmetallic elements (e.g., H, B, C, N, O, P and S) has gained ever-increasing attention since their introduction has been proven to effectively modulate the 3d-electronic configuration a