Non-metal redox kinetics: a reexamination of the mechanism of the reaction between hypochlorite and nitrite ions. Inorg. Chem. 1991; 30 :4845–4851.Johnson DW, Margerum DW. Non-metal redox kinetics: a reex- amination of the mechanism of the reaction between hypochlorite and nitrite ions. ...
Redox partner proteins of diheme cytochromes b are mainly iron-sulfur proteins or c-type cytochromes (Table 4; see also Figs 2 and 4 for examples). In many cases, electron transport catalyzed by diheme b-type cytochromes is coupled to the generation of a pmf across the membrane, either by...
The figure showed examples of human diseases where exosomal ncRNAs exert pivotal function. This figure was created with the aid of Servier Medical Art (https://smart.servier.com/) Full size image The roles of exosomal ncRNAs in cancers GLOBOCAN statistics report that approximately 14.1 million new...
The bis complexes were, in general, found to be square-planar, including the first examples of this geometry for paramagnetic complexes and different formal d(n) configurations. Several of the neutral and monoanionic tris complexes were found to have trigonal-prismatic coordination, the first time...
Prominent examples include 24M’s “SemiSolid” cell design, which Norwegian cell manufacturer Freyr is adopting171among others172. While 24M’s technology is being commercially adopted, it is notable that a major cell manufacturer has not licensed the technology but is instead being commercialized by...
Examples of classical divalent rare earth metal alkyl complexes (color online). 除了烷基化合物以外, 二价稀土金属的芳基和炔基配合物也有一些报道. 不过, 与烷基配合物不同的是, 芳基和炔基配合物一般是由稀土金属单质与转金属试剂或者炔烃等直接反应制得[47]. Deacon等[201]在2000年报道了第一例晶体结构...
For examples, some natural compounds can promote the lipid peroxidation by accelerating the iron-dependent Fenton reaction or LOX-catalyzed lipid oxidation. Artemisinin derivatives such as artesunate and dihydroartemisinin can trigger the ferritin degradation and cause elevated oxidative stress levels through ...
Cancer is a complex disease with diverse etiology; see examples of exposure related cancer in Additional file 1: Info Box 3, Table S2 in the supplementary). The neoplastic response depends not only on the kind of agent, its physicochemical and toxicological properties, the mode of exposure, ...
Examples include superoxide (O2−), peroxides (H2O2 and ROOH), and free radicals (HO· and RO·)19. In cells, GPXs use GSH as a cofactor to catalyze the decomposition of hydrogen peroxide and peroxide into H2O and corresponding alcohols. Under normal conditions, 15-LOX/PEBP1 and GPX4 ...
Among few examples, NMR-active ncAAs were incorporated into P450 enzymes to illuminate the role of conformational dynamics55. Recently, Kolev et al. utilized four ncAAs to scan the 11 active-site positions of CYP102A1, leading to unusual changes in regioselectivity and catalytic efficiency25. ...