Here, we discuss the wide-ranging potential of using OEEFs to catalyse and control a variety of non-redox reactions and impart selectivity at will. An OEEF along the direction of electron reorganization (the so-called reaction axis) will catalyse nonpolar reactions by orders of magnitude, ...
If the redox reaction is energetically downhill, as in the Daniell cell above, (i.e. spontaneous, with ΔG < 0) then the reaction can be used to power electric devices. Cells that power devices are known as galvanic cells. If the redox reaction is energetically uphill (i.e. non-...
redox potentials, redox reactions and thermodynamic favourabilityNAD-dependent dehydrogenase, and dehydrogenase specificityflavin-dependent dehydrogenases, oxidases, re-generation by molecular oxygenflavin-catalysed dehydrogenation mechanismsmonoamine oxidase inactivation and reaction mechanism...
Principles of chemistry And major topics covered include energy changes, stoichiometry, redox, electrolysis, and equilibrium. Regardless of the chosen pathway, students develop astrong foundationin chemistry with assessments that include...
REDOX Functional Group Interconversions: Selenium-Mediated Journey from Anilines to Nitroarenes and Back Again 16:20–16:40 Prof. Dr. Angelo Frongia Discoveries through Organocatalyzed, Brønsted Acid Catalyzed and Non-Catalyzed Transformations...
Non-enzymatic methylcyclization of alkenes Bifunctional methyltransferase–cyclases both transfer a methyl group to alkenes and induce cyclization—a process called methylcyclization. Now a non-enzymatic silver(I)-mediated electrophilic methylcyclization has been reported. The reaction uses commercial reagents...
Link：https://doi.org/10.31635/ccschem.023.202300614ed2 扫码在线阅读 扫描或长按左侧二维码，在线阅读全文 以下是本期每篇文章的导读和阅读链接：-Lithium Batteries. In this mini-review Jun Chen (陈军) and coworkers summarize the redox chemistry of different organic electrode materials in lithium ...
A new methodology is presented to study the kinetics of the galvanic replacement reaction between silver and gold, allowing, for the first time to our knowledge, real-time monitoring of the dynamics of this redox reaction by quantifying the main driving force, that is, the time- and concentrati...
-Perovskite Solar Cells. While solution processing significantly reduces the threshold and cost of perovskite solar cells, the intricate composition and nonequilibrium nucleation of the perovskite precursor can result in leaky films. Yanlin Song (宋延林), Na Wang (王娜), and coworkers provide a ...
Balancing redox equations Electrochemical cells and voltage The Nernst equation Spontaneous and non-spontaneous equations Chemical applications Labs Voltaic Cell Lab Students find the reduction potentials of a series of reactions using voltaic cells/multi-meters and build their own reduction potential table....