Wang, Origin of XPS binding energy shifts in Ni clusters and atoms on rutile TiO2 surfaces. Surface Science, 2008, 602, 2769.J.G. Tao, J.S. Pan, C.H.A. Huan, Z. Zhang, J.W. Chai, S.J. Wang, Origin of XPS binding energy shifts in Ni clusters and atoms on rutile TiO2 ...
what is the binding energy of 860.4eV corresponded to? it shifts 3.4eV in contrast to 857.0...
Therefore, the presence of a NiIII center was further confirmed by X-ray photoelectron spectroscopy (XPS), which shows an increase of the Ni 2p3/2 and 2p1/2 binding energies of ~1.5 eV for 5 versus 4, demonstrating the presence of a more oxidized Ni center (Supplementary Fig. 60)54...
The chemical environments of the synthesized Ni-based catalysts were studied by X-ray photoelectron spectroscopy (XPS). Supplementary Fig.5shows the high-resolution Ni 2pXPS spectra. For Ni/C, the peak at 852.1 eV was assigned to the Ni(0) species, and the peaks at 853.6 and 855.2...
XPS was used to characterize the composition of the resultant surfaces, while the surface morphology was examined using AFM [71,72]. Nanoindentation was used to examine the mechanical properties of the films [71]. XPS revealed that the only N compound formed in the nitrogen- implanted specimens...
其实XPS峰位置与电子环境有很大的关系，3价Ni一般会与2价Ni共存，会表现为两个峰（854-856之间）...
XPS measurements for Ni@C and Ni@C_OER:A. survey scan,B. Ni 2p core level spectra, andC. C 1s core level spectra Full size image 4.1Electronparamagnetic resonance spectroscopy For ions to be paramagnetic unpaired electrons are required. Nickel ions are capable of possessing from 1 to 3 th...
X-ray spectroscopy is highly convoluted by mixed oxides with various oxidation states, making it difficult to uniquely identify the subspecies resolved by the simulations. Nevertheless, we can verify the qualitative agreement between experiment and theory using XAS in addition to the XPS data already ...
Detailed analysis of XPS shows that nZVI can remove Ni(II) through adsorbing Ni(II) on the surface of nZVI and then reducing it to low-toxic Ni(0) as presented here [209]: (6.20)☰FeOH+Ni2+→☰FeO-Ni++H+ (6.21)☰FeO-Ni++H2O→☰FeONi-OH+H+ (6.22)☰FeO-Ni++Fe0+...
NEXAFS and XPS characterisation of carbon functional groups of fresh and aged biochars. Organic Geochemistry 77, 1–10 (2014). CAS Google Scholar Wang, H. et al. Capacitance effects superimposed on redox processes in molecular-cluster batteries: a synergic route to high-capacity energy storage....