In the presence of excess [H2O2] over (1), the reaction obeyed first-order kinetics and exhibited inverse proton dependence. [(NH3)5CoIII(渭-O2)CoIII((NH2)(NH3)4]4+(3), a conjugate base of 1, seems to be the kinetically reactive species and the cause for the observed inverse ...
The other is to form b-2-1m and NH3 through transition state b-2-1tM, owleciutlehs 2a01n8,e23n,exrgy barrier of 166.8 kJ/mol (pathway b-2). In pathway b-3, interm6 eofd1i1ate b-1-1m decomposes into NH2 radical and b-3-1m through homolysis of C-N bond, with an energy ...