[62] reported the mechanism for the NaBH4 hydrolysis over AgMWCNs, indicating the role of silver in the interaction with the B H4– ion. However, they did not indicate the role of silver species or the type of active centers in the BH4– and H2O adsorption and reac- tion...
Influence of various organic ligands on reduction of nitrobenzene by nanoscale zero-valent iron and its mechanism 有机配体对纳米零价铁还原硝基苯的影响与机理 通过FeSO4·7H2O与NaBH4反应,采用液相还原法制备纳米级零价铁(NZVI),并用XRD,SEM对其性能进行表征。研究了纳米零价铁还原硝基苯(NB)的动力学规律及...
And the hydrolysis reaction mechanism is turned out to be more explicit as Na2B4O5(OH)4·8H2O appears in the hydrolysis products. Since the preparation processes of these composites are simple and cost-effective and the hydrolysis of these composites achieves efficient hydrogen release, it is ...
4. Mechanism of NaBH4 Regeneration Using NaBO2·xH2O as Raw Materials The above three works [77,79,80] are new discoveries for direct regeneration of NaBH4 from the hydrated NaBO2 with high yield. Some common points were found in their mechanism studies. In all of the three works, a ...
The D-labeling experiments presented in Scheme 2 can be rationalized, taking into account the proposed mechanism. Thus, in the reduction of 1b with NaBH4 in methanol- d4, the major product is 3b-d1 having one H from a B-H bond and one D from the O- D functionality of the solvent....