Electrochemical conversion of CO2 into liquid fuels, powered by renewable electricity, offers one means to address the need for the storage of intermittent renewable energy. Here we present a cooperative catalyst design of molecule–metal catalyst interf
through density functional theory (DFT) calculation, we study the catalytic performance of the catalyst supported on nitrogen-doped carbon (NC) for the electrochemical reduction of CO2. We investigated anchoring a single
CO2reduction was first reported by Royer in 1870 when they observed the formation of formic acid in an aqueous medium [48]. Since then, the mechanism of electrochemical CO2RR has been gradually discovered and a number of different possible reaction intermediates are identified, which essentially det...
et al. Layered oxygen-deficient double perovskite as an efficient and stable anode for direct hydrocarbon solid oxide fuel cells. Nat. Mater. 14, 205–209 (2015). Article CAS PubMed Google Scholar Bai, S. et al. Highly active and selective hydrogenation of CO2 to ethanol by ordered Pd–...
2.2. Synthesis of single Pd atoms on metal oxide supports The noble metal catalysts like Pd and Pt (size 2–3 nm) are active for CO2 reduction but they suffer from high scarcity and low atomic efficiency. To address these problems, great efforts have been made to prepare single atoms ...
The relation between catalytic reactivities and metal/metal oxide ratios, as well as the functions of the metal and the metal oxides were investigated in the CO2 hydrogenation reaction over highly active Cox(CoO)1–x catalysts in operando. The catalytic reactivity of the samples in the CO2 methan...
The product was collected under an external magnetic field and washed several times with deionized water and ethanol under ultrasonication, then dispersed in a mixture containing 15 mL DMF, 0.12 g ZrCl4, and 0.09 g 2-aminoterephthalic acid under oscillation for 30 min to ensure uniform dispersion...
Reservoir solutions containing the Schiff base ligand (L1), glycine and their corresponding metal complexes, each formulated at a specific concentration of 1 X 10−3M, were created by precisely dissolving the appropriate weight in N, N‐dimethylformamide for Cu(II) complex and in ethanol for Sch...
However, our experiment found that Cu can easily turn to copper oxide and, hence, Pt appears to be the most promising among the plasmonic metals studied in this work. The enhancement of methanol yield from the modified TiO2 with metal loading could be explained by the formation of a Schottky...
Usually, the bimetallic or the oxide are prepared and their reaction with the P source follows (Figure 5). Table 4. The catalytic performance of different TMPs catalysts used in deoxygenation reactions of various reactants. Figure 5. Colloidal synthesis of ternary TMPs. Adapted from Ref [41...