4 CH3C6H4SO2OR + LiAlH4 → LiAl(O3SC6H4CH3)4 + 4 RHThus, tosylation followed by reduction allows for removal of a hydroxyl group.Likewise, TsCl is used to prepare sulfonamides from amines:CH3C6H4SO2Cl + R2NH → CH3C6H4SO2NR2 + HClThe resulting sulfonamides are non-basic and, when...
Draw the organic products formed when A is treated with each reagent: (1) H3O+; (2) -OH, H2O; (3) CH3CH2CH2MgBr (excess), then H2O; (4) LiAlH4, then H2O. Draw the organic products formed when C is treated with each reagent: (1) H3O+; (2) -OH, H2O; (3) CH3...
For example, ester groups were reduced to aldehydes and alcohols using suitable hydride reagents such as DIBAL-H, NaBH4, LiBH4, and LiAlH4 (Equation 56) <1997T739, 2003TA2717, 2004T441, 2004T6593, 2004TL4237, 2006T1171>. (56) The ester group on the isoxazolidine ring of 318 ...
What is the percent yield of a reaction that converts 1.000 kg of tol Predict the product of the reaction of p-methyl benzoic acid with the given reagent. LiAlH4,H3O+ (a) What reaction does augite have with hydrochloric acid? (b) If no reaction occurs, explain. What is the chemical...
What amide(s) will form the below amine on treatment with LiAlH4? Show how the given molecule can be prepared from a carbonyl compound and an amine (blue=N): What aldehyde or ketone is needed to prepare the below compound by an aldol reaction? What amine is formed by the ...
(e.g. HBr, especially concentrated aqueous HBr), or a nucleophile such as mercaptoacetic acid di-lithium salt, potassium hydroxide, potassium tert-butoxide, or sodium or potassium thiophenolate, or a reducing agent such as LiAlH4), at or above room temperature (e.g. at reflux) with or ...
What would the major organic product be for this reaction with LiAlH4 and D3O+? Name the major organic product of the reaction below. http://i.imgur.com/4oV3i89.jpg What are the organic products of the following reaction? What are the organic products of the following reactions? What is...
Answer to: Draw the structure of the product that is formed when the compound below undergoes a reaction with an excess of PhMgBr and then is...