(pentane-2,4-dionato-O,O)iron; Iron(III)-2,4-pentanedionate; Ironpentanedionate; Ironacetylacetonate; Iron iii 2,4-pentanedionate; pentane-2,4-dione-iron (3:1); (3Z)-4-hydroxypent-3-en-2-one-iron (3:1); iron(3+) tris[(2Z)-4-oxopent-2-en-2-olate]; Iron tri(...
The preparation of the second generation iron(II) complex Fe(hfa)2·TMEDA (hfa=1,1,1,5,5,5-hexafluoro-2,4-pentanedionate, TMEDA=N,N,N′,N′-tetramethylethylenediamine) is performed by reacting iron(II) chloride with Hhfa and TMEDA in two subsequent steps. Density functional theory data...
英文别名: Iron, tris(1,1,1-trifluoro-2,4-pentanedionato)-; TRIFLUOROACETYLACETONO IRON(III) SALT; TRIS(TRIFLUORO-2,4-PENTANEDIONATO)IRON(3); FERRIC(III) TRIFLUOROACETYLACETONATE; IRON(III) 1,1,1-TRIFLUORO 2,4-PENTANEDIONATE; IRON III TRIFLUOROPENTANEDIONATE; 1,1,1-trifluoropentane...
Interactions of various solvents with Fe(acac) 2+ , Fe(acac) 2 + and Fe(acac) 3 (the expression represents the solvated species: acac t- is the 2,4-pentanedionate ion, acetylacetonate ion) were investigated through observing v (Fe O) and v (C O) in resonance Raman spectra. In the...
In the title compound, [Fe(C5H6ClO2)3], the FeIII cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloropentane-2,4-dionate ligands in a slightly distorted octahedral environment. Fe—O bond lengths are in the range 1.9818 (18)–1.9957 (...
2. The catalyst composition of claim 1, where the iron-containing compound is an iron carboxylate, iron carbamate, iron dithiocarbamate, iron xanthate, iron β-diketonate, iron alkoxide, iron aryloxide, iron halide, iron pseudo-halide, iron oxyhalide, organoiron compound, or a mixtures thereof....
(η5‐pentamethylcyclopentadienyl)(2,4‐pentanedionate)iron(η5‐pentamethylcyclopentadienyl)(η5‐cyclopentadienyl)decomposition reactioncyclopentadienyllithiummethanolSummary This chapter contains sections titled: (η 5 -Pentamethylcyclopentadienyl)(2,4-pentanedionate)iron (η 5 -Pentamethylcyclopentadienyl)(η...
The invention concerns a method to prepare supported nanomaterials based on iron(III) oxide by the CVD technique, characterized by the fact that an iron(II) precursor, having general formula Fe(hfa)2TMEDA, where hfa indicates 1,1,1,5,5,5 - hexafluoro - 2,4 - pentanedionate and TMEDA ...
Reaction of FeCl3 with one equivalent of acac (acac = pentane-2,4-dionate) and KTpMe2 (TpMe2 = hydrotris(3,5-dimethyl-pyrazol-1-yl)borate) yielded TpMe2Fe(acac)Cl (3), which upon reaction with methanolic solution of sodium azide resulted in the formation of a six coordinate compound ...
Complexes Sc(Meacac)(3) and Fe(Meacac)(3) (Meacac is 3-methyl-2,4-pentanedionate anion) have been synthesized, and their crystal structures have been first determined by X-ray diffraction. The volatility and thermal stability of the obtained compounds have been studied. The temperature, ...