(acac = pentane-2,4-dionate) and KTpMe2 (TpMe2 = hydrotris(3,5-dimethyl-pyrazol-1-yl)borate) yielded TpMe2Fe(acac)Cl (3), which upon reaction with methanolic solution of sodium azide resulted in the formation of
Complexes Sc(Meacac)(3) and Fe(Meacac)(3) (Meacac is 3-methyl-2,4-pentanedionate anion) have been synthesized, and their crystal structures have been first determined by X-ray diffraction. The volatility and thermal stability of the obtained compounds have been studied. The temperature, ...
(acac = pentane-2,4-dionate) and K Tp~(Me2) (Tp~(Me2) = hydrotris(3,5-dimethyl-pyrazol-l-yl)borate) yielded Tp~(Me2)Fe(acac)Cl (3), which upon reaction with methanolic solution of sodium azide resulted in the formation of a six coordinate compound Tp~(Me2)Fe(acac)N_3 (4) ...