Mechanism of the hydrolysis of α-( p -nitrophenyl)cinnamonitrile derivativesGeneral BaseNucleophilic AdditionNaOAcHOAcCarbon Double BondThe rate constant hydrolysis of α-( p -nitrophenyl)cinnamonitrile(NCPN) and its derivatives have been determined at various pH, and the rate equation which can be...
The significance of nitrile hydrolysis reactions, proposed reaction mechanism, and potential applications of this type of reaction are reviewed.doi:10.1080/02603590214378EglinJudith L.Taylor & Francis GroupComments on Inorganic ChemistryJ. L. Eglin, Inorg. Chem. 23 , 23 (2002)....
1.Studies on Hydrolysis and Oxidation of Aromatic Nitriles;芳香腈水解反应及催化氧化反应研究 2.Investigation on hydrolysis of ethyl benzoate in the presence of cyclodextrin as microreactor环糊精微反应器中酯的水解反应研究 3.Research on Hydrolysis Reaction of Nitriles and Amides in Near-Critical Water近...
Careful disposal or recovery of metal complex residues is essential to prevent environmental contamination and ensure compliance with waste management regulations31. The proposed mechanism indicates that the copper metal complexes, particularly in the presence of an oxidizing agent like hydrogen peroxide (...
Cycloadditions of two thiocarbonyl ylides with α,β-unsaturated esters and nitriles: steric course and mechanism1,3-dipolar cycloadditions... R Huisgen,G Mloston,H Giera,... - 《Tetrahedron》 被引量: 71发表: 2002年 The One-Pot Wittig Reaction: A Facile Synthesis of ,β-Unsaturated Ester...
process for the preparation of amides by enzymatic hydrolysis of nitriles. In order to study the structure-reactivity relationship in the intramolecular catalyzed hydrolysis of amide, a series of aliphatic hydroxyamides was subjected to acid-catalyzed hydrolysis. Paper chromatogram verified that the hydro...
Erratum to: The catalytic mechanism of amidase also involves nitrile hydrolysis (FEBS 21159): [FEBS Letters 439 (1998) 325–328] The 4.6-kb region 5'-upstream from the gene encoding a cobalt-containing and amide-induced high molecular mass-nitrile hydratase (H-NHase) from Rhodococcus... M ...
The role of alpha-lactalbumin and the A protein in lactose synthetase: a unique mechanism for the control of a biological reaction Brew K, Vanaman TC, Hill RL. K Brew,TC Vanaman,RL Hill - 《Proceedings of the National Academy of Sciences of the United States of America》 被引量: 748发...
In this study, an attempt has been made to recover the lignin and enhance the sugar yield from the de-oiled Jatropha curcas waste (DJW) through alkaline hy
NitrileKineticsMechanismA series of mono-N-functionalized tetraaza macro-cycles having a nitrile group in their side chain have been synthesized and the kinetics and mechanism of the Cu2+ induced hydrolysis has been studied. Two factors were systematically varied: the length of the side chain and ...