CHOI et al.: " Hydrolysis of the nitrile group in alpha-aminophenylacetonitrile by nitrilase; development of a new biotechnology for stereospecific production of S-aplha-phenylglycine ", & ARCH. PHARMACOL RES. 1986, 9(1), 45-7Choi, S. Y. and Goo, Y. M.: Hydrolysis of the nitrile ...
ChemInform Abstract: Unusually Easy Hydrolysis of Nitrile Groups in 1,1,2,2-Tetracyanoethane under the Action of Pyruvic Acid A scheme for the unusually ready selective hydrolysis of three of the cyano groups in 1,1,2,2-tetracyanoethane to 2-cyanoethane-1,1,2-tricarboxamide by the... ...
The significance of nitrile hydrolysis reactions, proposed reaction mechanism, and potential applications of this type of reaction are reviewed.doi:10.1080/02603590214378EglinJudith L.Taylor & Francis GroupComments on Inorganic ChemistryJ. L. Eglin, Inorg. Chem. 23 , 23 (2002)....
Hydrolysis of the nitrile group in α-aminophenylacetonitrile by nitrilase; Development of a new biotechnology for stereospecific production ofS-α-phenylg... Phenylglycine was obtained as the sole metabolite when 伪-aminophenylacetonitrile was ted to the culture broth of Aspergillus furmigatus . The ...
et al. Efficient dehydration of aldoximes to nitriles catalyzed by a Lewis acid ionic liquid. Chem. Lett. 40, 396–397 (2011). Article CAS Google Scholar Babicka, M., Woźniak, M., Dwiecki, K., Borysiak, S. & Ratajczak, I. Preparation of nanocellulose using ionic liquids: 1-...
The unusual kinetic parameters for the latter complex are attributed to neighboring-group participation by the amide group.doi:10.1002/chin.198212325BALAHURA, R. JPURCELL, W. LJohn Wiley & Sons, LtdChemischer Informationsdienst
(bipy) moiety, due to an inductive effect, although to a less extent than ay a Fe II (CN) 5 or a Ru III (NH 3 ) 5 group, probably because of the π-back-bonding ability of Ru II , which makes the nitrile carbon atom of 4-pyCN less susceptible to the nucleophilic attack of ...
Biotransformation of β-amino nitriles: the role of the N-protecting group N-Tolylsulfonyl- and N-butyloxycarbonyl-protected beta-amino nitriles were prepared to study the effect of the N-protecting group on the biotransformation ... Margit Preiml,H. Hnig,N. Klempier - Journal of Molecular ...
The silanol-stopped diorganopolysiloxane fluids have been prepared, for example, by the carefully controlled hydrolysis of diorganodihalosilanes, by neutralization of metal ester and blocked linear diorganosiloxanes, by reaction of diorganopolysiloxanes with water and an organic nitrile in the presence...
Cyclic hydrolysis process of an aminonitrile compound to obtain a lactam by reaction of an aminonitrile of general formula (I): N --- C -R-NH2 (I) in which R represents a substituted aliphatic, cycloaliphatic, arylaliphatic radical or not, comprising 3 to 12 carbon atoms, with water, in...