CHOI et al.: " Hydrolysis of the nitrile group in alpha-aminophenylacetonitrile by nitrilase; development of a new biotechnology for stereospecific production of S-aplha-phenylglycine ", & ARCH. PHARMACOL RES. 1986, 9(1), 45-7Choi, S. Y. and Goo, Y. M.: Hydrolysis of the nitrile ...
Attempts to hydrolyse the nitrile group of 2-aminoadamantane-2-carbonitrile by mineral acid or alkali have been unsuccessful. However, treatment of the ami... M Paventi,FL Chubb,JT Edward - 《Canadian Journal of Chemistry》 被引量: 34发表: 1987年 Selective hydrolysis of the nitrile group of...
A series of aromatic dinitriles have been examined as substrates for an immobilised whole cell Rhodococcus sp. that catalyses the hydrolysis of nitrites to... John,Crosby,Jock,... - 《Journal of the Chemical Society Perkin Transactions》 被引量: 110发表: 1994年 Formation of Nitriles in the...
Simple amides ordinarily are prepared by reaction of acids or acid halides with ammonia or amines. They can also be produced by the reaction of water with nitriles. The characteristic reaction of covalent amides is hydrolysis (a chemical reaction with water), by which they are converted to ...
(bipy) moiety, due to an inductive effect, although to a less extent than ay a Fe II (CN) 5 or a Ru III (NH 3 ) 5 group, probably because of the π-back-bonding ability of Ru II , which makes the nitrile carbon atom of 4-pyCN less susceptible to the nucleophilic attack of ...
In this chapter, synthetic strategies for the enzymatic production and modification of amides will be reviewed, paying special attention to hydrolytic and synthetic processes using different enzymatic sources such as amidases, esterases, lipases, nitrile hydratases, and proteases. Comparisons with ...
1. The method of hydrolyzing a polymer of at least 90 percent by weight of a nitrile having a structure wherein n is an integer from zero to one (1) inclusive and up to 10 percent of another copolymerizable monomer, which comprises dispersing said polymer in pulverluent from in a mixtur...
This study presents a novel method for nanocellulose production using [Bmim]Cl as a green solvent, with enhanced hydrolysis efficiency achieved through the addition of a transition metal complex as a catalyst. The redox capability of the transition metal
Comparison of the Bioactivity of Two Glucoraphanin Hydrolysis Products Found in Broccoli, Sulforaphane and Sulforaphane Nitrile Epidemiological and laboratory studies suggest that dietary broccoli may prevent or delay a variety of cancers. Broccoli and other crucifers contain a rela... NV Matusheski,EH ...
Cyanoalkyl complexes of platinum(II) : III. Alcoholysis and hydrolysis of the CN groupdoi:10.1016/S0022-328X(00)91678-4 R Ros,J Renaud,R Roulet 被引量: 0发表: 1976年 Mechanistic and Stereochemical Investigation of Imino Ethers Formed by Alcoholysis of Coordinated Nitriles: X-ray Crystal Str...