Temperature dependent nuclear inelastic-scattering (NIS) of synchrotron radiation was applied to investigate both spin states of the spin-crossover complex [Fe(tpa)(NCS) 2 ] (tpa = tris(2-pyridylmethyl)amine). A remarkable increase of the iron–ligand bond stretching upon spin crossover has ...
Pressure induced high spin to low spin transition was observed at both ambient and low temperatures with continuous suppression of Fe magnetic moments under increasing pressure. The spin transition is closely related to the pressure induced tetragonal to orthorhombic structural transition. 展开 ...
high是什么意思??_百度知道 ... high-speed 高速的high-spin高自旋highstand 高水位期 ... zhidao.baidu.com|基于20个网页 2. 电子组态 ...low-spin)描述为四重态(quartet)的电子组态(high-spin)之激发态,以简化计算过程。 www.sciscape.org|基于2个网页...
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Troyer, “Susceptibility and low-temperature thermodynamics of spin-1/2 Heisenberg ladders,” Phys. Rev. B, 54, R3714–R3717 (1996). Article ADS Google Scholar R.M. Noack, S.R. White, and D.J. Scalapino, “Correlations in a two-chain Hubbard model,” Phys. Rev. Lett, 73, 882...
et al. Pressure-induced high-spin to low-spin transition in FeS evidenced by X-ray emission spectroscopy. Phys. Rev. Lett. 82, 3284–3287 (1999). CAS Google Scholar Fukazawa, H. et al. Suppression of magnetic order by pressure in BaFe2As2. J. Phys. Soc. Japan 77, 105004 (2008)...
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For high-spin multiplicity systems, inner-shell vacancies are usually implicitly present in the wave function. In the case of a resonance, ignoring the existence of this vacancy may lead to a breakdown in a variational or saddle-point calculation. In this work, model computations are carried out...