visible spectra/ low spin-high spin planar Ni(II) complexesphosphinic amidato ligandsbis(di-tert-butylphosphinic-N-tert-phenyl-amidato-N,O)Ni(II) complexspin tripletsinglet ground stateabsorption spectrumThe bis
whereas low spin complexes tend to contain paired electrons. In high spin complexes, the energy required to pair up two electrons is greater than the energy required to place an electron of that complex in a high energy level. In contrast, in low spin complexes, ...
High-Spin Low-Spin Behaviour of Co 2+ in Octahedral Coordination. I. Structure and Bonding in Tetrapyridine Complexes M II (tetrapy)X 2 路 2 H 2 O Single crystal X-ray studies of the compounds M II (tetrapy)(NO 3 ) 2 路 2 H 2 O [M II : Cu 2+ , Co 2+ ] were performed...
visible spectra/ magnetic high spin-low spin propertiesspectroscopic high spin-low spin propertiesFe(III) sulphide complexesextended structuresPolynuclear Fe(III) chain compounds with two bridging sulphur atoms show unusual magnetic and spectroscopic properties. The observed antiferromagnetism and the high-...
The axially symmetric hyperfine tensor depending on the π-properties of the ligands has been determined for the low-spin complexes. The spin polarization mechanism involving π-orbitals /xz,yz/ has been used for interpretation of the 14N superhyperfine tensor....
ChemInform Abstract: Nature of the Residual Paramagnetic Fraction in Discontinuous and Continuous High‐Spin (5T2) Low‐Spin (1A1) Transitions of Iron(II) Complexesdoi:10.1002/chin.198429051Moessbauer spectra (organic substances)E. + KOENIG
NMR signals for 19 F atoms introduced as substituents on the present heme in ferrous low-spin and high-spin and ferric low-spin complexes have been ... Y Yamamoto,Y Hirai,A Suzuki - 《Jbic Journal of Biological Inorganic Chemistry》 被引量: 18发表: 2000年 加载更多来源...
Exchange-coupled high-spin, low-spin and spin-crossover dicobalt(II) complexes of a pyridazine-containing Schiff-base macrocycle: control of cobalt(II) spi... A series of doubly pyridazine-bridged dicobalt(II) macrocyclic complexes, 1–7, is reported. The pyridazine-containing Schiff-b...
It is shown that, even though pairwise (Mn III -Mn III ) exchange interactions are antiferromagnetic or at best weakly ferromagnetic, it is still possible to prepare polynuclear manganese complexes which have high spin multiplicity ground states. The relatively large numbers of unpaired electrons in...
The filtered precursor solution was spin-coated onto a pre-cleaned Mo substrate at 2000 rpm for 30 s, followed by annealing on a hot plate at 280 °C for 2 min. This coating-annealing process was repeated 4 times in ambient conditions (25 °C, uncontrolled humidity, air). The...