Sulfoxide-alkene hybrids: A new class of chiral ligands for the Hayashi-Miyaura reaction - Thaler, Guo, et al.Sulfoxide-alkene hybrids: a new class of chiral ligands for the Hayashi-Miyaura reaction. Thaler Tobias,Guo Li-Na,Steib Andreas K,Raducan Mihai,Karaghiosoff Konstantin,Mayer Peter,...
Chiral phosphane alkene PAL for asymm Rh(I) arylboronate conjugate Hayashi-Miyaura conjugate enone enoate phenylationGrutzmacher, H
clavine alkaloidsRh(I)-catalyzed conjugate additionWe report the development of the diastereoselective rhodium(I)‐catalyzed intramolecular conjugate addition (Hayashi‐Miyaura reaction) of robust and easily handled 4‐pinacolboronic ester D‐tryptophan derivatives tethering an activated alkene as the ...