Pearson R.Hard and soft acids and bases, HSAB, Part Ⅰ, Fundamental principles. Journal of Chemical Education . 1968Pearson, R. G. ( 1968a ). Hard and soft acids and bases, HSAB, Part I . Journal of Chemical Education , 45 , 581 ....
HSAB(Hard and Soft Acids and bases) 软硬酸碱理论 在分析化学中的应用 ---陈德俊 一、理论原理 HSAB由1963年美国化学家Pearson根据Lewis酸碱理论和实验观察而提出 应用于无机化学、有机化学、催化反应、化学键理论等方面 HASB原则: 硬亲硬,软亲软,交界酸碱两边管 二、在分析化学中的应用 2.1、配合物的形成...
HSAB(Hard and Soft Acids and bases) 软硬酸碱理论 在分析化学中的应用 ---陈德俊 一、理论原理 HSAB由1963年美国化学家Pearson根据Lewis酸碱理论和实验观察而提出 应用于无机化学、有机化学、催化反应、化学键理论等方面 HASB原则: 硬亲硬,软亲软,交界酸碱两边管 二、在分析化学中的应用 2.1、配合物的形成...
Hard and soft acids and bases, HSAB, part I Focuses on the use of hard and soft acids principles in the study of chemical reactions. Properties of chemical systems; Characterization of soft and hard ... RG Pearson 被引量: 45发表: 1968年 Biosorption of lead (II) on modified barks explain...
The principle of hard and soft acids and bases (HSAB) has given chemists a broad understanding of the observed selectivity in a variety of reaction classes. As we become increasingly aware of the principle's serious limitations, this study provides an alternative approach. The distinction between ...
asoft ligands. Since sulfur has a very strong affinity for most[translate] aare responsible for the high adsorption property of chitosan.[translate] athe uptake capacity for many heavy metals because cadmium[translate] ametals according to the HSAB (hard and soft acids and bases)[translate]...
ChemInform Abstract: Adsorption and Corrosion Inhibition Effect of Anions Plus an Organic Cation on Iron in 1M HClO4 and the HSAB (hard and soft acids and ... Cheminformthe adsorption and corrosion inhibition effect of anions plus anorganic cation on iron in1M HClO4and the HASBprinciple. K.Ara...
Hard and Soft Acids and Bases, HSAB, Part II Underlying theories It must be emphasized again that the HSAB principle is intended to be phenomenological in nature. This means that there must be underlying theoretical reasons which explain the ehemical facts which the principle summarizes. It seems...
Barber, Application of the Hard and Soft, Acids and Bases (HSAB) theory to toxicant -- target interactions, Chem. Res. Toxicol. 25 (2012) 239-251.R.M. Lopachin, T. Gavin, A. Decaprio, D.S. Barber, Application of the hard and soft, acids and bases (HSAB) theory to toxicant-...
Using the quantum mechanical SCF MO LCAO and SCF X伪-SW methods, we have shown the effect of the hard and soft acids and bases principle in a new aspect: Inversion of the metal halides series BX 3 and AlX 3 (X=F, Cl, Br) on going from N- to P- and from O- to S-containing...