Hard and Soft Acids and Bases, HSAB, Part II Underlying theories It must be emphasized again that the HSAB principle is intended to be phenomenological in nature. This means that there must be underlying theoretical reasons which explain the ehemical facts which the principle summarizes. It seems...
HSAB(Hard and Soft Acids and bases) 软硬酸碱理论 在分析化学中的应用 ---陈德俊 一、理论原理 HSAB由1963年美国化学家Pearson根据Lewis酸碱理论和实验观察而提出 应用于无机化学、有机化学、催化反应、化学键理论等方面 HASB原则: 硬亲硬,软亲软,交界酸碱两边管 二、在分析化学中的应用 2.1、配合物的形成...
HSAB(Hard and Soft Acids and bases) 软硬酸碱理论 在分析化学中的应用 ---陈德俊 一、理论原理 HSAB由1963年美国化学家Pearson根据Lewis酸碱理论和实验观察而提出 应用于无机化学、有机化学、催化反应、化学键理论等方面 HASB原则: 硬亲硬,软亲软,交界酸碱两边管 二、在分析化学中的应用 2.1、配合物的形成...
Hard & Soft Acids and Bases A comprehensible explanation of the hard and soft acids and bases principle (HSAB principle) is described in this review first. Inhibition and stimulation ... RB Martin - American Cancer Society 被引量: 0发表: 2011年 Effects of anions on passive film breakdown of...
Hard and soft acids and bases, HSAB, part 1: Fundamental principles Using the principles of hard and soft acids and bases to estimate the strength and softness of an acid or base. Pearson,G Ralph - 《J.chem.educ》 被引量: 296发表: 1968年 HARD AND SOFT ACIDS AND BASES. Focuses on ...
Hard and Soft Acids and Bases Survey of Progress in Chemistry Volume 5, 1969, Pages 1-52 Purchase options CorporateFor R&D professionals working in corporate organizations. Academic and personalFor academic or personal use only. Looking for a customized option? Contact sales for special pricing for...
The principle of hard and soft acids and bases (HSAB) has given chemists a broad understanding of the observed selectivity in a variety of reaction classes. As we become increasingly aware of the principle's serious limitations, this study provides an alternative approach. The distinction between ...
Aqueous redox flow batteries with halide-based catholytes (where the halogen atom (X) is Br or I) are promising for sustainable grid energy storage. However, the formation of polyhalides during electrochemical charging and the associated phase separation
Electronegativity, acids, and bases—II : Size effects and the principle of hard and soft acids and bases The effect of size upon the strength of hard and soft acid-base interactions is examined and it is concluded that hard-hard interactions are especially stabilized by small size that favors...
The Hard and Soft Acids and Bases (HSAB) Principle - Insight to Reactivity and Sensitivity of Energetic Materials, Propellants Explos. Pyrotech. 2005, 30, 5.Koch E (2005) Acid–base interactions in energetic materials. I: The hard and soft acids and bases (HSAB) principle-insights to ...