A process for the selective high yield halogenation R--CH.sub. 3 wherein R is ##STR1## Si(Cl).sub.m (CH.sub.3).sub.n, wherein m is 1 to 3, n is 1 to 3 and m+n is 3; phenyl; or phenyl substituted with Cl, Br, F, OR.sup.1, SR.sup.1 or NO.sub.2 ; R.sup....
Free radical halogenation is not a suitable method for lobaratory synthesis of alkyl halides because of the following two reasons: (i) It gives a mixture of isomeric monohalogenated products whose boiling ponints are so close that they cannot be easily
Free radical halogenation of alkanes initiated by transition metal complexes - ScienceDirectLinkagehelicitymagnetohydrodynamicssolar magnetismReaction between halocarbons (particularly CCl 4) and hydrocarbons (particularly c-C 6H 12) in the presence of a range of low valent metal complexes have been ...
Reactive distillation process for free radical halogenationA process for the selective high yield halogenation R--CH.sub. 3 wherein R is ##STR1## Si(Cl).sub.m (CH.sub.3).sub.n, wherein m is 1 to 3, n is 1 to 3 and m+n is 3; phenyl; or phenyl substituted with Cl, Br, ...
Free radical halogenation of deuteriochloroformdoi:info:doi/10.1139/v69-782Tanner, Dennis D.Mosher, Melvyn W.Bunce, N. J.Canadian Journal of Chemistry
ation chlorination) Rev metal free select alkane adamantane functionalization rxn (radical oxygenation, halogenation chlorination)Rev metal free select alkane adamantane functionalization rxn (radical oxygenation, halogenation chlorination)Fokin, A ASchreiner, P R...
ChemInform Abstract: Free Radical Halogenation of Alkanes Initiated by Transition Metal Complexeshalogenation, dehalogenationNo abstract is available for this article.doi:10.1002/chin.198716141DAVIS, RDURRANT, J. L. AROWLAND, C. CWiley-BlackwellCheminform...
ChemInform Abstract: BRIDGED BROMINE AND CHLORINE FREE-RADICAL INTERMEDIATES. FREE RADICAL HALOGENATIONS OF 2-HALOBUTANEShalogenation, dehalogenationstructure (organic substanceshalogen compounds (acyclic compoundsNo abstract is available for this article.doi:10.1002/chin.197349195...
Hydrohalogenation produces the corresponding ethylene halohydrin, as shown in the equation In these and many analogous reactions, ethylene oxide acts as an alkylating agent for the introduction of the β-hydroxyethyl group, HOCH2CH2—. Because of this property, it is commonly used in industry and...
It was found that radical scavengers did not hamper the reaction (Fig. 8a), excluding the possibility of a radical pathway. In the next step, some reactions were carried out in order to ascertain if a chlorinated species is involved in the reaction. In this experiment, 3-chloro-2-...