observed regiochemistries indicate that the CF2H radical has a nucleophilic character similar to alkyl radicals, but the CF3radical is electrophilic in reactions with heterocycles. Here, the authors report DFT calculations, reproducing experimental selectivities and leading to an explanation of this ...
ChemInform Abstract: Unexpected Reversal in Stereochemistry of Radical Alkyne Cyclizationsteroidsstereochemistry (general, optical resolution)cleavage reactions, decomposition reactions, pyrolysisring closure reactionshalogenation, dehalogenationChemInform is a weekly Abstracting Service, delivering concise information at...