Electrochemical reduction (ECR) is a promising method to fabricate methanol (CH3OH) from carbon dioxide (CO2) where electrocatalyst, reactor configuration and electrode play an essential role. In this review, seven types of electrocatalysts, i.e., metal alloys, metal oxides, metal chalcogenides and...
Designing highly efficient electrocatalysts for electrochemical reduction of CO2(ERC) to value-added chemicals is a better approach to balance carbon emission. In this paper, through density functional theory (DFT) calculation, we study the catalytic performance of the catalyst supported on nitrogen-dope...
Electrochemical CO2reduction (ECR) is becoming a viable way of both storing electric energy and removing extra CO2in the atmosphere. However, unsatisfied product selectivity on cathode remains one of the major stumbling blocks present for commerciallization1,2. Owing to the uniform coordination structur...
Electrochemical CO2 reduction reaction (CO2RR) to liquid fuels is currently challenged by low product concentrations, as well as their mixture with traditional liquid electrolytes, such as KHCO3 solution. Here we report an all-solid-state electrochemical CO2RR system for continuous generation of high-...
The increasing energy demand, global climate change and foreseeable reduction in fossil fuel availability has sparked interest in the development of ways to produce synthetic fuel. One option is the conversion of CO2 to methane or methanol. The latter is already produced commercially at a factory in...
The field of electrochemical CO2 reduction is reviewed here, with sections on mechanism, formate (formic acid) production, carbon monoxide production, reduction to higher products (methanol, methane, etc.), use of flow cells, high pressure approaches, molecular catalysts, non-aqueous electrolytes, ...
Electrochemical carbon dioxide reduction reaction (CO2RR) provides a promising way to convert CO2 to chemicals. The multicarbon (C2+) products, especially
CO2and CO for binding to CoPc/MWCNT; (b) this competition is in favor of CO2; and (c) the CO formed upon CO2reduction is preferentially desorbed from the metal center rather than reduced to methanol. This also explains why methanol formation is essentially suppressed under a CO2atmosphere, ...
Electrocatalytic CO2 reduction reaction (CO2RR) is an attractive way to simultaneously convert CO2 into value-added fuels and chemicals as well as to store
摘要: Focuses on the electrochemical conversion of carbon dioxide to methanol with formate dehydrogenase and methanol dehydrogenase as biocatalysts. Pyrroloquinolinequinone as an electron mediator; Electrolysis of phosphate buffer solutions; Induction period; Role of enzyme and mediator in reduction processes....