the stage of discharge-ionization can be significant in the total overvoltage during the polarization of liquid metallic electrodes in molten chlorides depleted of electrochemically active particles (depending on the type of the dissipative structures that appear near the electrode/electrolyte interface). ...
Kinetics of the anodic reaction occurring during the electrolysis of molten nitrates on platinum electrodes at different temperaturesThe kinetics of the anodic reaction occurring during the electrolysis of molten nitrates on bright platinum electrodes has been studied. The kinetic parameters were obtained ...
Why does not water undergo electrolysis? Why does Na_2SO_4 undergo electrolysis? If you put copper metal into a solution of aluminum sulfate, what would happen? Briefly explain why different products are obtained from the electrolysis of molten NaCl and the electrolysis of a dilute aqueous solut...
The discharge of hydrogen ions on black platinum electrodes during the electrolysis of molten potassium bisulphate was examined by means of potential/current-density curves and observation of the decay of overpotential. The results indicate that the mechanism of reaction involves a recombination reaction ...
FluoridePFC emissionelectrochemical methodsgas chromatographySummary This chapter contains sections titled: Introduction Experimental Results and discussion Conclusiondoi:10.1002/9781118061886.ch13Guihua WangXiangsheng WangHongmin ZhuJohn Wiley & Sons, Ltd
This study investigated the ionic species and electrochemical reduction of silicate ions at a solid graphite electrode in molten NaCl鈥揅aCl2 eutectic melts with various concentrations of O2 ion at 1023 K. Silicate ion species in the mel... Y Ma,T Yamamoto,K Yasuda,... - 《Journal of the ...
The change of open-circuit potential of the Ni substrate during the alloying process was also measured after the electrolysis in the molten salts. It was found that the potential shifted to noble direction with time and several potentials showing constant values for a while were observed at -...
What substance is produced at the cathode during the electrolysis of molten calcium bromide, CaBr_2? Assume standard conditions. Current is applied to an aqueous solution of lithium sulfide. What is the cathode and what is the anode? What reactions take pla...
Polarization and mass transfer during the electrolysis of molten salts with liquid metallic electrodesMikhalevY. G.RUSSIAN METALLURGY METALLY C/C OF IZVESTIIA- AKADEMIIA NAUK SSSR METALLY
reduction of electrolysis current density and/or increase in electrolyte voltage due to a layer of anodic gas surrounding the anode and insulating it from the electrolyte, is suppressed of molten salts by vibrating the anode at frequency 1-300 pref. 50 Hz and amplitude 0.01-50, pref. 1.0 mm...