An electrolytic calorimeter employing a heat flux transducer (HFT) has been developed. By means of this apparatus the single electrode Peltier heat for the anodic chlorine evolution reaction in the electrolysis of molten NaCl-ZnCl 2 using a 尾 -alumina diaphragm was measured. The value of the ...
1.Understanding the Electrolysis Process: - Electrolysis is a chemical process that uses electricity to break down compounds. In this case, we are looking at the electrolysis of sodium chloride (NaCl) in two different states: molten and dissolved in water. ...
Formation of Intermetallic Compounds Layer Composed of Ni3Y and Ni5Y by Electrodeposition on Ni Using Molten NaCl^|^ndash;KCl^|^ndash;YCl3 Electrodeposition of Y on Ni and their alloying by molten salt electrolysis was attempted in an equimolar NaCl–KCl melt containing up to 4 mol% YCl3 at...
Furthermore, metallic Tm was extracted from molten salts on Cu electrode by potentiostatic electrolysis according to the deposition potential of four CuxTm compounds. The products were characterized by XRD and SEM-EDS, which showed that four Cu-Tm intermetallic compounds could be selectively prepared....
NaCl-KCl (NaKCl2), a strong candidate for fast reactors, is a good example of this incomparability. Fig. 3.1 exemplifies both the complexity and the extensive research conducted on binary, ternary, and n-ary fluoride salts throughout the decades of solid-state investigations. Janz et al., ...
In order to better understand the effect of this reaction on the NMR spectra, the authors have followed the evolution of the 93Nb chemical shift and linewidths with time when adding Nb metal to the melt NbCl5–(LiCl–NaCl)eut. It allows predicting the influence of the paramagnetic Nb4 + ...
Molten salt electrolysis is a proven technology for the extraction of metals—all the world's primary aluminum is produced in this manner. The unique prope... Sadoway,R Donald - 《Journal of Materials Research》 被引量: 77发表: 1995年 Preparation and thermal properties of porous heterogeneous ...
210A. Kolobovet al.·Chlorine Solutions in Molten Alkali ChloridesFig. 7. Temperature dependence of optical den-sityDred(ν=25000 cm−1) of saturated Cl2solutions in molten alkali chlorides. 1, NaCl;2, (NaCl-KCl)equimol;3,KCl;4,CsCl.Fig. 8. Influence of ionic composition of molten salt...
Molten oxide electrolysis (MOE) is proposed to replace traditional molten salt electrolysis using nonconsumable anode (inert anode) [5,12,13]. Meanwhile, MOE in molten fluorides has also been considered as a promising route for in situ use of lunar resources [[14], [15], [16]]. An ...
When performing electrolysis, the setup is done such that there is a supply of electrons, which will be used to push the non-spontaneous redox reaction to spontaneity. As such, the energy needed to allow the reaction to proceed to spontaneity is supplied by the...