The role ofdielectric constantε of a solvent regarding its capability to dissolve ionized solutes was pointed out in Section4.1(thedielectric constant is typically given as the relative dielectric constant to vacuum). Ahigher dielectric constantof the solvent correlates with a higher ability of the ...
This finding offers a new platform for calculating the hydration energy and orientation polarisation based on linear response theory for different kinds of ions in the solvent medium.Dielectric constant of solvents at nano to bulk regimes: linear response theory and statistical mechanics-based approaches...
Dependence of Ionic Mobility on Dielectric Constant of SolventBerns, D SFuoss, R M
Dielectric constantFree energyMembrane biochemistrySolventsIn this paper we are investigating the effect of the dielectric environment on atomic Born radii used ... M Feig,W Im,CL Brooks - 《Journal of Chemical Physics》 被引量: 204发表: 2004年 Silica and volatile-element metasomatism of Archean ...
The results showed that the relativedielectric constantof pork was decreased with increasing frequency, and the dielectric loss factor reached a minimum at 2500MHz. The relation between thedielectric constantof the solvent and the dissociation constant of Glycine was... ...
Calculations are carried out to determine the relation between the dielectric constant of solutions of large charged particles and the charge distribution on the particles. It is shown that if the hydrodynamic forces cause the particles to rotate about a point fixed in each particle, the dielectric...
Polarizability is the capacity of the solvent to induce any kind of electrostatic interaction with a dissolved solute, which is a measure of the “polarity” of the solvent. Hence, polarizability is a macroscopic property just like the dielectric constant. Using the Kamlet–Taft solvatochromic method...
Dielectric constantMolecular dynamics (MD) simulations in NaI solutions, where the solvent has been represented by the Stockmayer fluid, were performed as a... VA Payne,M Forsyth,MA Ratner,... - 《Journal of Chemical Physics》 被引量: 59发表: 1994年 The ELBA force field for coarse-grain ...
the dielectric constant of solvent and the intensity ratio of Fermi resonance.And the empirical formula was obtained by curve fitting.The equation of ... 张留洋,王志刚,王月萌,... - 《Spectroscopy & Spectral Analysis》 被引量: 8发表: 2009年 Semi-empirical expression for the dielectric constant...
Dispersion polymerization in non-polar solvent: Evolution toward emerging applications in electrophoretic displays, where one of the numerous requirements is that the particle systems be suspended in low dielectric constant, non-polar solvents... AP Richez,HN Yow,S Biggs,... - 《Progress in Polymer...