Higher conductivities can be obtained by simply increasing n and/or the electrical mobility μ. For example, in n-type TCOs, the oxygen vacancies constitute one of the main defects inducing high carrier concentrations. The hybridization of s-orbitals—that compose mainly the conduction band minimum...
NBO analysis and charge-model calculations support the presence of sd σ hybridization and electron transfer to the copper ion in case of the first two ligands.doi:10.1016/S0166-1280(99)00073-1A.M. El-NahasN. TajimaK. HiraoJournal of Molecular Structure Theochem...
结果表明,具有Cu-N4 SAs的Fe AC表现出优异的ORR性能,在碱中具有0.92 eV的半波电势,在酸中具有0.80 eV的半波电势,并且在锌-空气电池中具有214.8 mW cm-2的高功率密度。相关工作以“Modulating Electronic Structures of Iron Clusters through Orbital Rehybridization by Adjacent Single Copper Sites for Efficient ...
The first shell of the Ag + ion is filled with four NH 3 molecules and the resulting tetrahedral Ag +(NH 3) 4 complex is solvated by subsequent NH 3 molecules through hydrogen bonding. A coordination number of 2 for Cu + can be ascribed to extensive 4s-3d hybridization in Cu +, ...
Nitrogen-doped carbon quantum dots-decorated 2D graphitic carbon nitride as a promising photocatalyst for environmental remediation: A study on the importance of hybridization approach. J. Environ. Manag. 2020, 255, 109936. [Google Scholar] [CrossRef] Gao, Y.; Chen, F.; Chen, Z.; Shi, H...
This result is consistent with the exchange of H+ in HPW by Cu2+/Zn2+ and it may be the cause of the reduction in the amount of Brönsted acidity of xHPW/Ti observed by NH3-TPD after the hybridization with CZA. The migration of Cu2+/Zn2+ species from CZA to xHPW/Ti could ...