Ruthenium [CpRu(MeCN)3]PF6 cat Decarbonylative Cyclization of 1,6-DiyneGonzalezRodriguez, CVarela, J ACastedo, LSaa, C
The preparation of CpRu(MeCN)(3)PF6 using an easily assembled continuous flow reactor is described. This scalable, reproducible method provides the title compound in excellent yield and purity, and eliminates the need for any purification steps. Under our optimized conditions, the residence time ...
[CpRu(MeCN)3]PF6 CpRuPF6 quinaldic mild select O-allylether O-deallylKitamura, M
Scalable and Robust Synthesis of CpRu(MeCN)3PF6 via Continuous Flow Photochemistrydoi:10.1556/jfchem.2011.00004Alicia C. GutierrezTimothy F. JamisonAkadémiai Kiadó, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic Publishers B.V....
Ligand exchange of 2 in acetonitrile with (Z,Z)-1,5-cyclooctadiene (COD) produces [CpRu(η2:η2-COD)(MeCN)]PF6 (5; with X-ray crystal structure); with chelating phosphanes (P−P), complexes [CpRu(P−P)(MeCN)]PF6 are selectively generated, and starting with a 1,4-diazadiene...
CpRu(PPh3)+ [CpRu(PPh3)(MeCN)]PF6 cat allylester O-deallyl deprotectKitamura, M