合成了一系列的5个双齿含氮杂芴类配体,利用五个含氮杂芴配体,结合*配体膦配体,与Cu(CH3CN)4PF6配位组装,成功合成出8个新颖的一价铜配合物,分别是:[Cu(DF)(TPP)2PF6](1)、[Cu(DF)[TPP(o-CH3)](CH3CN)PF6](2)、[Cu(ACE)(TPP(P))PF6]2(DDF)(3)、[Cu(DF)(DPEphos)PF6](4)、[Cu(dedaf...
Under mild conditions, the copper(I) complex [CuI(TMPA)CH3CN]PF6 (TMPA=tris(2-pyridyl-methyl)amine), reacts stoichiometrically with benzyl and allyl halides, and [alpha]-halo-ketones to produce near quantitative yields of carbon-carbon reductively coupled products bibenzyls, diolefins or di...
Under mild conditions, the copper(I) complex [CuI(TMPA)CH3CN]PF6 (TMPA=tris(2-pyridyl-methyl)amine), reacts stoichiometrically with benzyl and allyl halides, and α-halo-ketones to produce near quantitative yields of carbon-carbon reductively coupled products bibenzyls, diolefins or diketones,...
The formation of a gel-like material only upon addition of [Cu(CH3CN)4]PF6 to the most concentrated library ( c mon = 60 m M ) was explained as arising from the presence of significant amounts of trimeric and higher oligomeric macrocycles C i ( i ≥ 3), acting as cross-linking ...
The treatment of [Mo2(pyphos)4] (1) (pyphos = 6-diphenylphosphanyl-2-pyridonate) with [Cu(NCCH3)4](PF6) in CH2Cl2 and CH3CN mixed solvent (1:5 v/v) led to the formation of a linear tetranuclear cluster, cis-[Mo2{Cu(NCCH3)2}2][(pyphos)4](PF6)2 (cis-2a-PF6), as a...
Further addition of a molar equivalent of 1 to 2b gave rise to a pentanuclear {CuPt4} complex of [Cu{Pt2(PPh3)4(μ3-S) 2}2]PF6, 3. Complex 3 was also obtained from the direct 2: 1 addition of 1 to [Cu(CH3CN)4]PF6. Complexes 2 and 3 have been characterized by IR and 31...