Process for the conversion of nitrile compounds to carboxylic acids and corresponding esters The present invention relates to aprocess for the conversion of hydrocarbon compounds comprising at least one nitrile functional group to compounds comprising atleast one carboxyl functional group and also to a ...
Green synthesis of nitriles using non-noble metal oxides-based nanocatalysts. Nat. Commun. 5, 4123 (2014). Article CAS Google Scholar Gooβen, L. J. & Rodríguez, N. A mild and efficient protocol for the conversion of carboxylic acids to olefins by a catalytic decarbonylative elimination ...
Mild Conversion of aldono- and aldurononitriles into the corresponding amides and/or carboxylic acids by an immobilized nitrilase complex such as, for example, 2 - pyrrolidone, succinimide, milk acid amide and fatty acid amides, with hydrogen to the corresponding amines can be hydrogenated... A...
Single-site cobalt catalysts at new Zr12(µ3-O)8(µ3-OH)8(µ2-OH)6 metal–organic framework nodes for highly active hydrogenation of nitroarenes, nitriles and isocyanides. J. Am. Chem. Soc. 139, 7004–7011 (2017). Article CAS Google Scholar Manna, K. et al. Chemoselective ...
ofesters,amides,carboxylicacids,amines.andnitrogen—containingheterocycles『11.Therearemanyreportedproceduresforthesynthesisofnitriles,suchasnucleophilicsubstitutionofalIcylhalideswithmetalcyanideforalky1nitrilesI21.andtheSandmeyerandammoxidationreactionforaromaticnitrilesfbenzonitriles)『31.Dehydrationofaldoximestonitriles...
of (X) has been disclosed by Zhang et al in Tetrahedron Lett. 1996, 37, 4455-4458 and J. Org. Chem. 1997, 62, 2466-2470, which describe amidine formation from a nitrile using the Pinner reaction. Although this process has been able to produce compounds of formula (X) on a multi...
Direct Conversion of Substituted Pyrrole‐2‐carboxylic Acid Methyl Esters to Their 2‐Carbonitrile Analoguespyrrole derivativespyridine derivativescyanation, nitrile formationChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals...
Examples of these inert solvents include without limitation, acetic acid, propionic acid and other carboxylic acids. Other solvents include hydroxycarboxylic acids, nitriles such as acetonitrile, benzonitrile, amides such as acetamide, dimethylformamide (DMF), etc. Preferred solvents are acetic acid and...
The dye may be retained by the semiconductor nanoparticle layer in any form or manner. For example, a typical method dissolves any of the above-mentioned dyes in a solution such as alcohols, nitriles, nitromethane, halogenated hydrocarbon, ethers, dimethyl sulfoxide, amides, N-methylpyrrolidone, ...
of HCN to aldehydes to afford, generally, an epimeric pair of cyanohydrins, with subsequent reduction of the nitrile group of the latter under conditions where the formed imine is concurrently hydrolyzed to its corresponding aldose, as shown by the equation, --CHO+HCN➝--CHOHCN➝--CHOHCHO...