First continuous flow synthesis of pioneering CO2capture MOF UTSA-16(Zn).Record production rate of 173g/h, a 77-fold increase on previous batch method.Fe3O4nanoparticles incorporated in flow synthesis (3–11%).Highest production rate of any magnetic framework composite to date (152g/h)....
A versatile continuous-flow synthesis of highly functionalized 1,2,4-oxadiazoles starting from carboxylic acids is reported. This process was applied to the multistep synthesis of imidazo[1,2-a]pyridin-2-yl-1,2,4-oxadiazoles, using a three reactor, multistep continuous-flow system without ...
Continuous Flow-Processing of Organometallic Reagents Using an Advanced Peristaltic Pumping System and the Telescoped Flow Synthesis of (E/Z)-Tamoxifen A new enabling technology for the pumping of organometallic reagents such as n-butyllithium, Grignard reagents, and DIBAL-H is reported, which utilise...
Additionally, the generation of large quantities of unstable intermediates, such as diazo species, can be avoided through the use of smaller continu- ous flow reactors yet still allow the generation of large quan- tities of final product. The continuous flow synthesis of azo compounds has been ...
micro-flowsystemcyclohexeneoxideDCCEpoxidation reaction catalyzed by dicyclohexylcarbodiimide(DCC) was realized in a microflow system, resulting in cyclohexene oxide with high yields. In this study, the epoxidation process of cyclohexene in MFS was investigated in detail. The optimal yield was obtained ...
CM-ELFlow Electrochemical Reactor Summary Electrochemical synthesis is the use of electrical energy to drive chemical change; using electricity to replace toxic and costly chemical reagents. This allows cleaner and cheaper syntheses with greater production efficiency and at reduced cost. Electrochemical ...
Here we design a Pickering-emulsion-droplet-integrated electrode to facilitate the continuous-flow electrocatalytic synthesis of cyclohexanone oxime. The emulsion droplets provide an ideal localized interfacial microenvironment for electrocatalysts, characterized by the orientational ordering of water molecules ...
The invention is directed to a continuous flow chemical method for the solid phase synthesis of peptides at elevated temperatures and pressures. The invention is based on the unexpected finding that using the continuous flow technology to the solid phase peptide synthesis the amino acid excess can ...
Few examples of combined microwave heating and continuous flow systems for MOF synthesis at the laboratory scale have been reported. These include; a gas liquid segmented flow reactor capable of producing ∼90 g/h/L of MOF-74(Ni) with a STY of 2160 kg/m3/d; [27] a plug flow rea...
The present invention provides various methods for the synthesis of chemical species in a microreactor environment. In some cases, reaction products of the present invention may be