Asymmetric Synthesis Syntheses of [Co(bpy)3]2+ yield racemic solutions because the Δ- and Λ-enantiomers are stereochemically labile. However, crystallization and attrition-enhanced deracemization can give homochiral crystal batches of either handedness in quantitative yield. Subsequently, solvent-free ...
产品名称:Co(III)-bpy-TFSI钴盐 英文名称:Co(III)(bpy)3(TFSI)3 complex 分子量:1367.92 外观:黄色粉末 纯度:大于99% 包装及详细说明: 最小包装: 1克 钴基(III)三联吡啶双三氟环酰亚胺盐配合物用于钙钛矿太阳能电池HTM层的P型掺杂剂.低温氧化镍旋涂液(2wt%) ...
f Ru–Co complex is (bpy) Ru(phen-C H -phen)Co(bpy) . 2 2 4 2 g Control experiment. Both the Ru and Co complexes were dissolved in the mixed solvent. b heterogeneous system as shown in Table 1 (Run 1) and Fig. 3. As the lifetime of the metal complexes was extended ...
C_2H_2则几乎全抑制了体系的放氢.因此,可以认为乙炔等底物的还原以及放氢是在同一活性中心上发生的.C_3D_3的加氢实验指出,C_2H_3侧配位于Co~I上发生顺位加氢反应.由动力学实验得知,乙烯生成的初速与溶液的pH值的关系呈高斯型;对乙炔分压为一级反应;对Co(bPy)~(2+)浓度为零级反应.初步讨论了光助单电子...
在光敏剂[Ru(bpy)3]Cl2·6H2O 作用下,Co-TBAPy可以在可见光范围内催化CO2还原为0.14~1.65比例范围可控的合成气,尤其是CO:H2 = 1:2 或 1:3的合成气的精确制备将利于甲醇和甲烷的合成,但在MOFs基光催化剂中甚少报道。DFT计算还进一步揭示了水在可控比例合成气合成中的重要性。这一工作为工业领域中CO2光催化...
CAS号:67201-98-3 分子式:C44H32CoN8 分子量:731.726 结构式 卟啉产品目录: 四(对-甲基苯基)卟啉合银(TMPP-Ag) TPP-Zn/OTZrP、TPP-Ag/OTZrP、TMPP-Zn/OTZrP和TMPP-Ag/OTZrP 5-氰基-10,15,20-三(四氰基苯)卟啉(CN-TCPP) 钌化卟啉配合物[Ru(bpy)2(MPyTMPP)Cl](简称Rub2P) ...
The catalysts consist of zeolite Y-encapsulated Ru(bpy)32+ (bpy = 2,2'-bipyridine) sensitizers in close proximity to TiO2 nanoparticles on the same support. The photophysical properties of Ru(bpy)32+ within the zeolite supercages were investigated at different loadings of Ru(bpy)32+ and TiO2...
The binding of Co(bpy)2dppz3+ to calf thymus DNA was investigated by using absorption and emission spectroscopy, DNA melting techniques, cyclic voltammetry, viscosity and electro phoresis measurements, where bpy is 2,2′-bipyridyl, dppz is dipyrido[3,2-a:2′,3′-c] phenazine. The binding ...
5-(4-(4-羧基-2,2′-联吡啶-4′-甲酰氨基)苯基)-10,15,20-三苯基卟啉(H2TPP-NHCO-BpyCOOH) 5-(4-(异烟酰氨基)苯基)-10,15,20-三苯基卟啉(apPyTPP) 5-(4-3-氰基苯甲酸酰亚 胺基)苯基-101,5,20-三苯基卟啉配体(CBTPPH2) 5-(4-氨基)苯基-10,15,20-三苯基卟啉(MATPP) ...
四-[3-甲氧基-4-(N-咔唑)正己氧苯基]卟啉(4C6-TPP)|水溶性阳离子卟啉 卟啉光敏剂的分子器件[Zn(TPP-NHCO-BpyCH3)]-[Pt11Cl2] 5-(4-(4-甲基-2,2′-联吡啶-4′-甲酰氨基)苯基)-10,15,20-三苯基卟啉(H2TPP-NHCO-BpyCH3) 5-(4-(4-羧基-2,2′-联吡啶-4′-甲酰氨基)苯基)-10,15,20...