Asymmetric Synthesis Syntheses of [Co(bpy)3]2+ yield racemic solutions because the Δ- and Λ-enantiomers are stereochemically labile. However, crystallization and attrition-enhanced deracemization can give homochiral crystal batches of either handedness in quantitative yield. Subsequently, solvent-free ...
产品名称:Co(III)-bpy-TFSI钴盐 英文名称:Co(III)(bpy)3(TFSI)3 complex 分子量:1367.92 外观:黄色粉末 纯度:大于99% 包装及详细说明: 最小包装: 1克 钴基(III)三联吡啶双三氟环酰亚胺盐配合物用于钙钛矿太阳能电池HTM层的P型掺杂剂.低温氧化镍旋涂液(2wt%) ...
钌化卟啉配合物[Ru(bpy)2(MPyTMPP)Cl](简称Rub2P) 四苯基卟啉烷氧基铝(TPPAIOR) 5,10-二(对-氨基)四苯基卟啉(简称TBP) 中间体化合物2-甲酰基-5,10,15,20-四苯基卟啉(FTPP) 5,10,15,20-四(4-溴苯基)铁卟啉(FeTBrPP) meso-四(4-羟基苯基)卟啉(H2THPP) 5,10,15,20-四(4-羟基苯基)锌卟...
在光敏剂[Ru(bpy)3]Cl2·6H2O 作用下,Co-TBAPy可以在可见光范围内催化CO2还原为0.14~1.65比例范围可控的合成气,尤其是CO:H2 = 1:2 或 1:3的合成气的精确制备将利于甲醇和甲烷的合成,但在MOFs基光催化剂中甚少报道。DFT计算还进一步揭示了水在可控比例合成气合成中的重要性。这一工作为工业领域中CO2光催化...
To reveal highly efficient photocatalytic properties of an artificial photosynthesis material [Re(CO)(bpy){P(OEt)}](PF), we have directly observed the photo-induced relaxation dynamics and reductive quenching process of the photo-excited state on a photosynthesis material in Triethanolamine (TEOA) ...
C_2H_2则几乎全抑制了体系的放氢.因此,可以认为乙炔等底物的还原以及放氢是在同一活性中心上发生的.C_3D_3的加氢实验指出,C_2H_3侧配位于Co~I上发生顺位加氢反应.由动力学实验得知,乙烯生成的初速与溶液的pH值的关系呈高斯型;对乙炔分压为一级反应;对Co(bPy)~(2+)浓度为零级反应.初步讨论了光助单电子...
The binding of Co(bpy)2dppz3+ to calf thymus DNA was investigated by using absorption and emission spectroscopy, DNA melting techniques, cyclic voltammetry, viscosity and electro phoresis measurements, where bpy is 2,2′-bipyridyl, dppz is dipyrido[3,2-a:2′,3′-c] phenazine. The binding ...
Density Functional Theory/Time-dependent DFT Studies on the Structures, Trend in DNA-binding Affinities, and Spectral Properties of Complexes [Ru(bpy)... Studies on the electronic structures and trend in DNA-binding affinities of a series of Ru(II) complexes [Ru(bpy)2(p-R-pip)]2+ (bpy ...
其中通过将[ReI(CO)3(dcbpy)Cl] (H2L4, bpy=2,2′-联吡啶)作为配体引入骨架中形成MOF 4. 光催化CO2还原过程如图2所示, 光催化实验结果表明该催化剂在饱和CO2的乙腈(MeCN)溶液中能选择性将CO2转化为CO, CO2转化为CO的转化数(TON)为10.9, 是均相络合物L4的3倍. 同时对形成的MOFs在光催化还原CO2的可循环...
The results of the characterization procedure have been compared and found very similar to analogous complexes of rhenium such as the monometallic Re(bpy)(CO) 3 Cl where bpy = 2,2'-bipyridine. Tandem infrared spectroelectrochemical analysis confirmed the reversibility of the reduction processes at ...