PROBLEM TO BE SOLVED: To obtain a very useful catalyst which gives excellent chirality in the asymmetric reduction of a ketone to the secondary alcohol.BLACKLOCK THOMAS Jトマス ジェー.ブラックロックJONES TODD Kトッド ケー.ジョーンズ...
Interactive 3D chemistry animations of reaction mechanisms and 3D models of chemical structures for students studying University courses and advanced school chemistry hosted by University of Liverpool
前手性酮的还原,reduction of... ... ) Chiral reduction 手性还原 ) prochiral ketones 前手性酮 ) prochiral ketone 前手性酮 ... www.dictall.com|基于2个网页 例句 释义: 全部,前手性酮 更多例句筛选 1. Asymmetric Reduction of Prochiral Ketones under Condition of Solid-Liquid Phase-transfer Cataly...
This stabilization manifests as a substantial energy reduction of −19.6 kcal/mol (Fig. 7a), demonstrating the essential role of non-covalent interactions (NCI) in steering the reaction pathway toward high stereoselectivity. Progressing from Int1-SR to the final epoxide necessitates overcoming ...
The reduction of unhindered ketones, such as acetylenic ketones, with B-3-pinanyl-9-borabicyclo[3.3.1]nonane (Alpine-Borane, prepared by hydroboration of α-pinene with 9-BBN) provides a simple means of forming chiral, nonracemic alcohols of known absolute configuration in high enantiomeric ...
An introduction of chiral centers into acyclic systems based on stereoselective ketone reduction. Acc. Chem. Res. 17, 338-344 (1984).Oishi, T, Nakata, T (1984) Acc Chem Res 17: pp. 338Oishi, T. and Nakata, T. (1984). An introduction of chiral centers into acyclic systems based on ...
2) asymmetric reduction of prochiral ketones 前手性酮的不对称催化还原反应 1. Chiral squaric acid derivatives:synthesis and application to catalytic asymmetric reduction of prochiral ketones; 手性方酸衍生物的合成及在前手性酮的不对称催化还原反应中的应用研究进展 更多例句>> 3) Reduction of ketone ...
Immobilization of chiral oxazaborolidine catalyst over highly ordered 3D mesoporous silica with Ia3d symmetry for enantioselective reduction of prochiral k... Immobilization of chiral oxazaborolidine catalyst over highly ordered 3D mesoporous silica with Ia3d symmetry for enantioselective reduction of pro...
Shafiee, A.; Motamedi, H.; King, A., Purification, characterization and immobilization of an NADPH-dependent enzyme involved in the chiral specific reduction of the keto ester M, an intermediate in the synthesis of an anti-asthma drug, Montelukast, from Microbacterium campoquemadoensis (MB5614)...
Laboratory of Applied BiocatalysisMicrobial Cell FactoriesDu PX, Wei P, Lou WY, Zong MH. Biocatalytic anti-Prelog reduction of prochiral ketones with whole cells of Acetobacter pasteurianus GIM1.158. Microb Cell Fact. 2014;13:84.Du, P. X., P. Wei, W. Y. Lou, and M. H. Zong (2014)...