The chemical equilibrium constants were calculated for the reactions to produce glycerol carbonate from glycerol. The theoretical calculation was compared with the experimental results for the transesterification of glycerol with dimethyl carbonate. Transesterification of glycerol with cyclic carbonates or alkyl...
When this concentration is exceeded, glycerol appears in the urine and causes an osmotic diuresis roughly equivalent to the volume adrninistered.9 Adverse Reactions Notable adverse reactions of glycerol in man include intravascular hemolysis, hemoglobinuria, renal damage, hyperglycemia, and hyperosmolality...
A preliminary study of the acid and base properties of the Zn-Sn-Beta zeolite indicated that the introduction of Zn into the Sn-Beta zeolite enhanced both Lewis acid and base sites, which further inhibits a series of side reactions related to fructose dehydration to HMF and its subsequent ...
The SAMPLE agent uses a Gaussian process (GP) model to build an understanding of the fitness landscape from limited experimental observations. The model must consider the protein function of interest, in addition to inactive ‘holes’ in the landscape arising from destabilization of the protein struc...
Chen*, “Controlling reaction pathways of selective C-O bond cleavage of glycerol”, Nature Communications, (2018) accepted. X. Yang, J. Nash, J. Anibal, M. Dunwell, S. Kattel, E. Stavitski, K. Attenkofer, J.G. Chen*, Y. Yan*, and B. Xu*, “Mechanistic Insights into ...
on starchy cereals, usually with a high proportion of malted barley dependent on the beer type to be produced. The cereals used can be kilned in many ways, resulting in a non-enzymatic browning mechanism (Maillard reactions), creating darker cereals giving more color and flavors to the beer....
Bilik V (1972) Reactions of saccharides catalyzed by molybdate ions. II. Epimerization of d-glucose and d-mannose. Chem Zvesti 26:183–186 CAS Google Scholar Gunther WR, Wang Y, Ji Y, Michaelis VK, Hunt ST, Griffin RG, Román-Leshkov Y (2012) Sn-beta zeolites with borate salts catal...
of construction and fabrication as well as external fuel combustion to provide the heat necessary to drive the endothermic reactions. Carbon dioxide exists in both syngas from the tube side and flue gas from the furnace side, which complicates carbon capture scheme for natural gas reforming ...
Application of ferrocene in chemical reactionsApr 8,2022 Introduction Ferrocene is an organic transition metal compound with aromatic properties[1]. Its chemical formula is Fe(C5H5)2. It is an orange-yellow powder at room temperature and has a camphor odor. Melting point 172℃-174℃, boiling ...
reactions proceeding via the Mars-van-Krevelen mechanism (A4) for production of organic compounds such as alkenes, a combined chemical looping approach using two or more different types of solid intermediates (B2), for desulphurisation of industrial or effluent streams by means of a sulphur ...