Crystal Field Theory simply: a ligand lone pair(孤对电子) is modelled as a point charge that repels electrons in the d orbitals of the central metal ion.下图显示的是金属d轨道的空间构型:2. 正八面体配位体Octahedral complexes本章节基础知识详参数学几何中的群论。在此我不多做解释。我很喜欢几何...
In octahedral complexes, two orbitals are in the high energy level (collectively known as eg) and three orbitals are in the lower energy level (collectively known as t2g). In tetrahedral complexes, the opposite occurs; three orbitals are in the higher energy level and two in the lower ...