The agostic bond between one hydrogen atom of a phenyl group and the rhodium central ion distorts the ligand sphere from a five-fold geometry to an octahedral complex, which is most likely caused by the the semi-classical dispersion corrections in GFN2-xTB on which we relied for this explorat...
Roles of Mo surface dopants in enhancing the ORR performance of octahedral PtNi nanoparticles. Nano Lett. 18, 798–804 (2018). CAS Google Scholar Cao, L. et al. Differential surface elemental distribution leads to significantly enhanced stability of PtNi-based ORR catalysts. Matter 1, 1567–...
With octahedral TiIVcomplex as the building unit, this study reports on the first 3D anionic titanium-based COF (Ti-COF-1) with an edge-transitive (6, 4)-connected soc topology. Ti-COF-1 exhibits high crystallinity, superior stability, and large specific surface area (1000.4m2g-1). More...
The OER catalytic performance of Ru nanocrystals with different structures was investigated to explore the relationship between catalytic activity and crystal structures [63]. It is reported that the face-centered cubic (fcc)-Ru octahedral nanocrystals exhibit the best performance compared with fcc-Ru t...
The peaks at 711.2 eV and 724.6 eV binding energy correspond to Fe 2p3/2 and Fe 2p1/2, with the related satellite peaks at 719.1 eV and 732.3 eV, attributed to Fe3+ at octahedral sites in α-Fe2O344. Each peak was fitted by several components, reflecting a complex...
The high-spin Fe(II) species in an octahedral crystal field with t2g4eg2 electron configuration dominate the VBM in this material, whereas the bpee linker (as opposed to the bridging sq species or inorganic node) make up the conduction band edge (Figure 7E). Another noteworthy example is ...
The BMR freeness conjecture for the tetrahedral and octahedral families We prove the validity of the freeness conjecture of Brou\\'e, Malle andRouquier for the generic Hecke algebras associated to the exceptional complexreflect... Chavli,Eirini - 《Communications in Algebra》 被引量: 9发表: 201...
). LDHs consists of octahedral-brucite-like M(OH)2 layers (shown in Fig. 2e) and charge balancing anions (An−) such as CO32−, Cl−, SO42−, and RCO2− locating in the interlayer space [46,47]. In addition, there are many other 2D materials obtained from various layered ...
Direct observation of elemental fluctuation and oxygen octahedral distortion-dependent charge distribution in high entropy oxides. Nat. Commun. 13, 2358 (2022). Article CAS PubMed PubMed Central Google Scholar Witte, R. et al. High-entropy oxides: an emerging prospect for magnetic rare-earth ...
Here, we show the synthesis method for complex 3D nanoframes wherein two-dimensional (2D) dual-rim nanostructures are engraved on each facet of octahedral nanoframes. The synthetic scheme proceeds through multiple executable on-demand steps. With Au octahedral nanoparticles as a sacrificial template, ...