The agostic bond between one hydrogen atom of a phenyl group and the rhodium central ion distorts the ligand sphere from a five-fold geometry to an octahedral complex, which is most likely caused by the the semi-classical dispersion corrections in GFN2-xTB on which we relied for this explorat...
During the use of tannic acid as a cross-linker, three galloyl groups from the tannic acid molecule react with each of Fe III ion forming an octahedral complex [91]. The tannin-metal complex formation is significantly influenced by the initial pH value. A tannin-metal mono-complex is ...
For example, the coordination number of the cobalt ion is six, with the coordinated atoms in an octahedral arrangement. [Co(NH3)4Cl2]+ can arrange the ligands around Co3+ in two different ways, as cis and trans stereoisomers (Fig. 2a). Similarly, Rodríguez-Fernández [7] discussed the ...
The BMR freeness conjecture for the tetrahedral and octahedral families We prove the validity of the freeness conjecture of Brou\\'e, Malle andRouquier for the generic Hecke algebras associated to the exceptional complexreflect... Chavli,Eirini - 《Communications in Algebra》 被引量: 9发表: 201...
a MOF consisting of metal-oxide node pillars in an octahedral arrangement connected by bdc linkers in the perpendicular direction forming a ‘wine rack’ shaped structure. This MOF is known to occur in two primary phases: a low temperature ‘narrow’ pore phase and a high temperature ‘large’...
(ChCl)/glycerol.The ChCl/glycerol DES not only tailored the morphology of the as-prepared precursor by template effect but also inhibited its hydrolysis,ensuring the successful fabrication of octahedral NiCo–NH_(3) complex precursor with high yield.The NiCo–NH_(3) complex precursor was ...
studied the HER activity of single-sided gold nanocubes (NCs) and nano-octahedral (ODs) as exhibited in Fig. 6e and f, respectively [25]. Voltammetry of single Au NCs and Au ODs was performed (Fig. 6g) and showed a similar trend to macroscale CV experiments. Evidently, compared to Au ...
Structurally sophisticated octahedral metal complexes as highly selective protein kinase inhibitors. The generation of synthetic compounds with exclusive target specificity is an extraordinary challenge of molecular recognition and demands novel design str... L Feng,Y Geisselbrecht,S Blanck,... - 《Journal...
Synthesis and characterization of ternary alkaline-earth transition-metal hydrides containing octahedral [Ru(II)H6]4− and [Os(II)H6]4− complexes. J. Solid State Chem. 93, 256–262 (1991). Article CAS Google Scholar Gao, W. et al. Barium hydride-mediated nitrogen transfer and ...
Here, we show the synthesis method for complex 3D nanoframes wherein two-dimensional (2D) dual-rim nanostructures are engraved on each facet of octahedral nanoframes. The synthetic scheme proceeds through multiple executable on-demand steps. With Au octahedral nanoparticles as a sacrificial template, ...