The reduction of carboxylic acid esters to alcohols is commonly effected with a stoichiometric amount of a highly reactive metal-hydride reagent (e.g.LiAlH4).The amount of waste generated by this procedure would decrease strongly through the use of H2 as the reducing agent.The homogeneous ...
A novel and efficient procedure for the preparation of allylic alcohols from α,β-unsaturated carboxylic esters using LiAlH4/BnCl A new and efficient method for the reduction of α,β-unsaturated carboxylic esters to allylic alcohols utilizing LiAlH4/BnCl is described. Various α,β-u... X Wan...
methyl sulfide and LiAlH4 differ considerably in their reactivity toward other functional groups5, the borane methyl sulfide reagent constitutes a valuable alternative to LiAlH4 for chemically modifying nitroxide carboxylic acids which also bear other functional groups susceptible toward reduction by LiAlH4...
-phenylcaproicacid Chapter143=> IUPACNames Remove-efromalkane(oralkene)name,add-oicacid.Thecarbonofthecarboxylgroupis#1.ClOCH3CH2CHCOH PhCHC HCOOH 2-chlorobutanoicacidtrans-3-phenyl-2-propenoicacid(cinnamicacid)=> Chapter144 NamingCyclicAcids Cycloalkanesbondedto-COOHarenamedas...
CHAPTER 11 CARBOXYLIC ACID Chapter11CarboxylicAcidandSubstitutedCarboxylicAcid CarboxylGroup:R-COOH (H3C)2HCH2CCH3CHCOOH 布洛芬抗炎镇痛药 COOHOCOCH3 阿司匹林解热镇痛药 I、ClassificationandNomenclature Classification 结构AliphaticSaturatedAromaticUnsaturated 数目：一、二元(mono/dicarboxylicacid)、多元(poly-)取代...
An interesting, recently reported complementary observation is that the superacid CF3SO3H (trifluoromethanesulfonic acid; triflic acid) is able to protonate cations such as 6.59 Dicationic species are thus produced, with ring-opening occurring at the distal cyclopropane CC bond, which...
reduction, hydrogenationcatalysis, phase‐transfer catalysiscarbonic acid derivatives (benzene compoundscarbonic acid and carbonic acid derivatives (also CO, CS2 etccarboxylic acids (acyclic compoundscarboxylic acids (benzene compoundsA comprehensive overview on homogeneous catalytic hydrogenation of carboxylic ...
(1:4) derivative in presence of quinoline and reduction of the product with LiAlH4, followed by oxidation with MnO2 in petroleum ether, gives 4-methyl-4-(tetrahydro-pyranyloxy) - hexadiene - (2:5) - al - 1, which affords 1 - methoxycarbonyl - 1:5 - dimethyl-7-bromoheptatriene-(1:3...
作者: Joy Sinha,Suman Layek,Gagan C. MandalManish Bhattaharjee 摘要: Reaction of α,β-unsaturated aromatic carboxylic acids with KBr and H_2O_2 in the presence of Na_2MoO_4·2H_2O in aqueous medium affords β-bromo alkenes in high yield. 年份: 2001 收藏...