Fourier transform IR spectrum and photoreactivity of the C 3 O 2 :HCl complex isolated in solid argonC3o2, hcl complexFourier transform ir spectrumPhotoreactivitySolid argonDouble-doping experimentsNear-infrared spectraCarbon suboxideMonatomic matrices...
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Compared to H2-assisted activation mode, the direct dissociation of CO2 into carbonyl (*CO) with a simplified reaction route is advantageous for CO2-related synthetic processes and catalyst upgrading, while the stable C = O double bond makes it very challenging. Herein, we construct a subna...
Thus, the spectrum was consistent with the imino structure for a polymer having a high molecular weight (Figures 1 and 2). It was found that the polyimine prepared in m- cresol was not easily redissolved in the same solvent once isolated. The insoluble part increased with increasing reaction...
The X-ray photoelectron spectroscopy (XPS), temperature-programmed desorption (TPD) and infrared spectrum (IR) results suggest that besides the oxygen species of BSCF and LSCF, the OH-related species can be detected on BCFZY, which can play a promoting role in oxygen catalysis activity. The ...
The spectrum of the weakly-bound van der Waals complex Ar-CO has been observed for the first time in the region of the CO vibrational overtone, using a long-path (180m) low-temperature (64K) absorption cell and a Fourier transform infrar... ARW Mckellar - 《Molecular Physics》 被引量:...
Fe(dmpe)2 differs drastically from Ru(dmpe)2 in its absorption spectrum and its reactivity. Most notably, the rate constant for reaction with H-2 is a factor of 7500 smaller for Fe(dmpe)2 than for Ru(dMpe)2. In contrast, reactions of both complexes with CO are diffusion-controlled. ...
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