High-throughput fast microwave Vorbruggen BSA TMSOTf glycosylation syn nucleoside libraryBookser, B CRaffaele, N B
BSA, when used as a catalyst in combination with a series of ionic liquids with fluoride anions, facilitates the synthesis of α, β-unsaturated esters. Mechanism investigation through GC-MS reveals that BSA converts into onium amide, which acts as a strong base for α-H abstraction. Additiona...