Srinivas, Selective Oxidation of Benzyl Alcohol Over Copper Phthalocyanine Immobilized on MCM-41, Catal. Lett. 128 (2009) 434-442.A. Hamza, D. Srinivas, Selective oxidation of benzyl alcohol over copper phthalocyanine immobilized on MCM-41, Catal. Lett. 128 (2009) 434-442....
we use N-unprotected amino acid esters as nucleophiles in reactions with benzyl alcohol derivatives. A ternary catalyst comprising a chiral aldehyde, a palladium species, and a Lewis acid is used to promote the reaction. Both mono- and polycyclic benzyl alcohols are excellent benzylation reagents....
The quantum chemical parameters of 19 kinds of benzyl alcohol derivatives are calculated by B3 LYP method with PCM solvent model. The relationship between molecular activity and their inhibitory activities on aspergillus niger larvae are studied. It is found that the linear relationship between their ...
ChemInform Abstract: FUNGAL METABOLITES. PART 8. ISOLATION OF 2‐METHOXY‐6‐(3,4‐DIHYDROXYHEPTA‐1,5‐DIENYL)BENZYL ALCOHOL 来自 Wiley 喜欢 0 阅读量: 16 作者:AW Dunn,RAW Johnstone 摘要: A new-metabolite of Aspergillus variecolor has been isolated and identified as having the structure (1)...
The metabolic soft spot is assumed to be the benzyl alcohol function which could be prone to oxidation. Further investigation of the effect of different 6‐aryl groups on potency and metabolic stability should be performed. Table 3. In vitro and in vivo ADME and pharmacokinetics of compound ...
Fusel alcohols (more than two carbon atoms) are mainly produced by yeast during fermentation (Figure 4). The few exceptions, such as hexanols, benzyl alcohol, and 2-phenylethanol, are usually derived from the raw material. The most abundant alcohols are 1-propanol, 2-methyl-1-propanol, 2-...
“IPA” refers to isopropyl alcohol; IPA″ refers to isopropyl amine; “Isomer 1” refers to the first eluting isomer under the conditions proscribed herein; “Isomer 2” refers to the second eluting isomer under the conditions proscribed herein; “LC/MS” refers to liquid chromatography followed...
For the recycle test, carbon cloth modified by compound 1 was washed three times with acetonitrile and ethyl alcohol, and dried for the next cycle. 3. Results and Discussion 3.1. Synthesis and Structure Compound 1 was prepared by the hydrothermal reaction of K7HNb6O19·13H2O, VOPO4·2H2O,...
The catalytic properties of cobalt oxide are due mainly to its Lewis acid nature [14]. Additionally, several reports [14,41,42] indicate that the Co3O4 oxide systems used as catalysts in oxidation reactions and described in the literature have a spinel structure, which is conformed with both...
Reaction III A is normally conducted by treating a benzene solution of a benzyl alcohol with thionyl chloride at reflux temperature for about 1 hour. This can also be performed in other inert solvents such as toluene, chloroform, tetrachloride and the like or by using excess thionyl chloride as...