Intermolecular forcesOxidation of benzyl alcohol is one of the industrial reactions utilized to produce chlorine-free benzaldehyde. Interestingly, supported gold nanoparticle catalysts are efficient towards the oxidation reaction of alcohol without involving any solvents, hence following the terms of green ...
(12 L), and dried at 45° C. under reduced pressure to give 2.41 kg of 9a as a white solid, 89.8% overall yield from 4-bromobenzyl alcohol (26a), m.p. 88° C. (DSC peak temperature). LC-MS: calc [M+H] 434, found, m/z 434;1H NMR (700 MHz, CD3OD): δ 1.42 (s, 6H...
intermolecular forcesmolecular vibrationorganic compoundsorganic molecule configurations and dimensionsspectral line breadth/ OH stretching vibrationbenzyl alcohol conformersfundamental OH stretching doubletmolecular conformersThe fundamental OH stretching doublet in the i.r. spectra of a series of a monomeric ...
(FTIR) spectrum revealed that the major structural moiety of BITC was embedded in the cavity of α−CD, except for the thiocyanate group. FTIR and X-ray diffraction analysis further verified that intermolecular interactions were formed between the BITC−α−CD and CS film matrix. The ...